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Quantum Monte Carlo Study of Small Hydrocarbon AtomizationEnergies

Journal Article · · Molecular Physics
OSTI ID:890630

A new temperature-profile method was recently developed for analyzing perturbed flow conditions in superheated porous media. The method uses high-resolution temperature data to estimate the magnitude of the heat-driven liquid and gas fluxes that form as a result of boiling, condensation, and recirculation of pore water. In this paper, we evaluate the applicability of this new method to the more complex flow behavior in fractured formations with porous rock matrix. In such formations, with their intrinsic heterogeneity, the porous but low-permeable matrix provides most of the mass and heat storage capacity, and dominates conductive heat transfer. Fractures, on the other hand, offer highly effective conduits for gas and liquid flow, thereby generating significant convective heat transfer. After establishing the accuracy of the temperature-profile method for fractured porous formations, we apply the method in analyzing the perturbed flow conditions in a large-scale underground heater test conducted in unsaturated fractured porous tuff. The flux estimates for this test indicate a significant reflux of water near the heat source, on the order of a few hundred millimeter per year-much larger than the ambient percolation flux of only a few millimeter per year.

Research Organization:
Ernest Orlando Lawrence Berkeley NationalLaboratory, Berkeley, CA (US)
Sponsoring Organization:
USDOE Director. Office of Science. Office of Basic EnergySciences. Chemical Sciences Geosciences and Biosciences Division; National Science Foundation. CREST Program Grant HRD-0318519
DOE Contract Number:
AC02-05CH11231
OSTI ID:
890630
Report Number(s):
LBNL--57069; BnR: KC0301020
Journal Information:
Molecular Physics, Journal Name: Molecular Physics Journal Issue: 3 Vol. 104; ISSN MOPHAM; ISSN 0026-8976
Country of Publication:
United States
Language:
English

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