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Toward understanding the structural basis of cyclin-dependentkinase 6 specific inhibition

Journal Article · · Journal of Medicinal Chemistry
DOI:https://doi.org/10.1021/jm0600388· OSTI ID:887205

CDKs are key players in cell cycle control, and genetic alterations of CDKs and their regulators have been linked to a variety of cancers. Hence, CDKs are obvious targets for therapeutic intervention in various proliferative diseases, including cancer. To date, drug design efforts have mostly focused on CDK2 because methods for crystallization of its inhibitor complexes have been well established. CDK4 and CDK6, however, may be at least as important enzymes for cell cycle regulation and could provide alternative treatment options. We describe here two complex structures of human CDK6 with a very specific kinase inhibitor, PD0332991, which is based on a pyrido[2,3-d]pyrimidin-7-one scaffold, and with the less specific aminopurvalanol inhibitor. Analysis of the structures suggests that relatively small conformational differences between CDK2 and CDK6 in the hinge region are contributing to responsible for the inhibitor specificity by inducing changes in the inhibitor orientation that lead to sterical clashes in CDK2 but not CDK6. These complex structures provide valuable insights for the future development of CDK specific inhibitors.

Research Organization:
Ernest Orlando Lawrence Berkeley NationalLaboratory, Berkeley, CA (US)
Sponsoring Organization:
USDOE Director, Office of Science; National Institutes ofHealth
DOE Contract Number:
AC02-05CH11231
OSTI ID:
887205
Report Number(s):
LBNL--60698
Journal Information:
Journal of Medicinal Chemistry, Journal Name: Journal of Medicinal Chemistry Vol. 49; ISSN JMCMAR; ISSN 0022-2623
Country of Publication:
United States
Language:
English

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