Palladium (II) catalyized polymers of norbornene and acrylates
Patent
·
OSTI ID:880587
Homopolymers or copolymers of acrylates, homopolymers or copolymers of norbornenes, and copolymers of acrylates with norbornenes, may be prepared by contacting acrylate and/or norbornene monomer reactant under polymerization conditions and in the presence of a solvent with a catalyst system consisting essentially of a Pd(II) dimer component having the formula: where L is a monodentate phosphorus or nitrogen ligand, X is an anionic group, and R is an alkyl or aryl group.
- Research Organization:
- Pennsylvania State University, University Park, PA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG02-84ER13295
- Assignee:
- The Penn State Research Foundation (N/A)
- Patent Number(s):
- 6,300,440
- Application Number:
- 09/565,137
- OSTI ID:
- 880587
- Country of Publication:
- United States
- Language:
- English
Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate
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journal | February 1998 |
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