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Heterogeneous Reactor Model for Steam Reforming of Methane in a Microchannel Reactor with Microstructured Catalysts

Journal Article · · Catalysis Today, 110(1-2):92-97

Microstructured catalysts used for methane steam reforming in microchannel reactors are mathematically described and experimentally demonstrated under realistic process conditions. A heterogeneous model has been developed with a graphical interface to represent the three dimensions of the microchannel reactor. Porous metal substrates (FeCrAlY) were used to form engineered catalysts with active precious metal (Rh) for methane steam reforming. Two types of structures were evaluated in the microchannel reactors and simulated with the developed heterogeneous reactor model. Local temperature and methane concentration profiles within the structures are illustrated to show the correlation of the catalyst structure and its performance. Such a modeling technique provides a convenient and flexible method to evaluate variables in designing more efficient catalysts for the highly endothermic steam reforming reactions, as the desired mass and heat transfer characteristics are achieved.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
876903
Report Number(s):
PNWD-SA-6873; 17504
Journal Information:
Catalysis Today, 110(1-2):92-97, Journal Name: Catalysis Today, 110(1-2):92-97
Country of Publication:
United States
Language:
English

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