Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Electrolyte treatment for aluminum reduction

Patent ·
OSTI ID:874955

A method of treating an electrolyte for use in the electrolytic reduction of alumina to aluminum employing an anode and a cathode, the alumina dissolved in the electrolyte, the treating improving wetting of the cathode with molten aluminum during electrolysis. The method comprises the steps of providing a molten electrolyte comprised of ALF.sub.3 and at least one salt selected from the group consisting of NaF, KF and LiF, and treating the electrolyte by providing therein 0.004 to 0.2 wt. % of a transition metal or transition metal compound for improved wettability of the cathode with molten aluminum during subsequent electrolysis to reduce alumina to aluminum.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA
Assignee:
Northwest Aluminum Technologies (Seattle, WA)
Patent Number(s):
US 6497807
Application Number:
09/721,845
OSTI ID:
874955
Country of Publication:
United States
Language:
English

References (3)

Principles of Aluminum Electrolysis book January 2016
The Transfer of Nickel, Iron, and Copper From Hall Cell Melts to Molten Aluminum journal January 1996
The wettability of TiB2-based cathodes in low-temperature slurry-electrolyte reduction cells journal May 1998