Supported organometallic catalysts for hydrogenation and Olefin Polymerization

Marks, Tobin J.; Ahn, Hongsang

Title: Supported organometallic catalysts for hydrogenation and Olefin Polymerization

Patent · Mon Jan 01 00:00:00 EST 2001

OSTI ID:873757

Marks, Tobin J.; Ahn, Hongsang

Novel heterogeneous catalysts for the which hydrogenation of olefins and arenes with high conversion rates under ambient conditions and the polymerization of olefins have been developed. The catalysts are synthesized from Ziegler-type precatalysts by supporting them on sulfate-modified zirconia.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-86ER13511

Assignee:: Northwestern University (Evanston, IL)

Patent Number(s):: 6,235,918

Application Number:: 09/364,216

OSTI ID:: 873757

Resource Relation:: Patent File Date: 1999 Jul 29

Country of Publication:: United States

Language:: English

References (11)

Nature of hydrous zirconia and sulfated hydrous zirconia Clearfield, A.; Serrette, G. P. D.; Khazi-Syed, A. H. Catalysis Today, Vol. 20, Issue 2 https://doi.org/10.1016/0920-5861(94)80008-1	journal	June 1994
Solid superacid catalysis: kinetics of butane isomerization catalyzed by a sulfated oxide containing iron, manganese, and zirconium Zarkalis, A. S.; Hsu, C. -Y.; Gates, B. C. Catalysis Letters, Vol. 29, Issue 1-2 https://doi.org/10.1007/BF00814269	journal	January 1994
Acid Sites in Sulfated and Metal-Promoted Zirconium Dioxide Catalysts Adeeva, V.; Dehaan, J. W.; Janchen, J. Journal of Catalysis, Vol. 151, Issue 2 https://doi.org/10.1006/jcat.1995.1039	journal	February 1995
The H/D exchange reaction occurring at low temperature between small alkanes and D2O exchanged solid acids. III. The role of alkenes and carbenium ions as reaction intermediates Sommer, Jean; Habermacher, David; Hachoumy, Mohammed Applied Catalysis A: General, Vol. 146, Issue 1 https://doi.org/10.1016/0926-860X(96)00168-8	journal	October 1996
Sulfated Zirconia-Based Strong Solid-Acid Catalysts: Recent Progress Song, Xuemin; Sayari, Abdelhamid Catalysis Reviews, Vol. 38, Issue 3 https://doi.org/10.1080/01614949608006462	journal	August 1996
Electrophilic chlorination of methane over superacidic sulfated zirconia Batamack, Patrice; Bucsi, Imre; Moln�r, �rp�d Catalysis Letters, Vol. 25, Issue 1-2 https://doi.org/10.1007/BF00815410	journal	January 1994
IR characterization of sulfated zirconia derived from zirconium sulfate Platero, E. Escalona; Mentruit, M. Pe�arroya Catalysis Letters, Vol. 30, Issue 1-4 https://doi.org/10.1007/BF00813670	journal	January 1995
The mechanism of conversion of hydrocarbons on sulfated metal oxides. Part IV. Kinetics of the reaction of methylcyclopentane on sulfated zirconia11Part III: A. Ghenciu and D. Fărcas̡iu, Catal. Lett., 44 (1997) 29. Part II: A. Ghenciu and D. Fărcas̡iu, J. Mol. Catal. 109 (1996) 273. Fărcaiu, Dan; Li, Jing Qi; Kogelbauer, Andreas Journal of Molecular Catalysis A: Chemical, Vol. 124, Issue 1 https://doi.org/10.1016/S1381-1169(97)00067-8	journal	September 1997
Microcalorimetric Characterization of Structural and Chemical Heterogeneity of Superacid SO ₄ /ZrO ₂ Systems ^† Bolis, V.; Magnacca, G.; Cerrato, G. Langmuir, Vol. 13, Issue 5 https://doi.org/10.1021/la950938j	journal	March 1997
Hydrogen Exchange between Sulfated Zirconias and per Deutero- Benzene as Characterization of the Surface Acidity Armendariz, H.; Sanchez Sierra, C.; Figueras, F. Journal of Catalysis, Vol. 171, Issue 1 https://doi.org/10.1006/jcat.1997.1780	journal	October 1997
One-Step Synthesis and Characterization of Zirconia-Sulfate Aerogels as Solid Superacids Ward, D. A.; Ko, E. I. Journal of Catalysis, Vol. 150, Issue 1 https://doi.org/10.1006/jcat.1994.1319	journal	November 1994

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supported
organometallic
catalysts
hydrogenation
olefin
polymerization
novel
heterogeneous
olefins
arenes
conversion
rates
ambient
conditions
developed
synthesized
ziegler-type
precatalysts
supporting
sulfate-modified
zirconia
ambient conditions
heterogeneous catalyst
olefin polymerization
metallic catalyst
organometallic catalyst
metallic catalysts
conversion rates
heterogeneous catalysts
olefin polymer
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Title: Supported organometallic catalysts for hydrogenation and Olefin Polymerization

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References (11)

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