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Thin transparent conducting films of cadmium stannate

Patent ·
OSTI ID:873685

A process for preparing thin Cd.sub.2 SnO.sub.4 films. The process comprises the steps of RF sputter coating a Cd.sub.2 SnO.sub.4 layer onto a first substrate; coating a second substrate with a CdS layer; contacting the Cd.sub.2 SnO.sub.4 layer with the CdS layer in a water- and oxygen-free environment and heating the first and second substrates and the Cd.sub.2 SnO.sub.4 and CdS layers to a temperature sufficient to induce crystallization of the Cd.sub.2 SnO.sub.4 layer into a uniform single-phase spinel-type structure, for a time sufficient to allow full crystallization of the Cd.sub.2 SnO.sub.4 layer at that temperature; cooling the first and second substrates to room temperature; and separating the first and second substrates and layers from each other. The process can be conducted at temperatures less than 600.degree. C., allowing the use of inexpensive soda lime glass substrates.

Research Organization:
Midwest Research Institute
DOE Contract Number:
AC36-83CH10093
Assignee:
Midwest Research Institute (Kansas City, MO)
Patent Number(s):
US 6221495
OSTI ID:
873685
Country of Publication:
United States
Language:
English

References (16)

Physical properties of cadmium-tin oxide films deposited by d.c. reactive sputtering journal April 1979
Effect of Heat Treatment on Electrical and Optical Properties of Cd 2 SnO 4 Films journal March 1993
Preparation, electrical properties and optical characterization of Cd2SnO4 and CdIn2O4 thin films as transparent and conductive coatings journal October 1987
CdOSnO2 Thin Films Prepared by DC Sputtering with Oxide Targets journal July 1991
Optical and Electrical Properties of Cd 2 Sn O 4 : A Defect Semiconductor journal July 1972
Optical properties of cadmium stannate thin film prepared by pyrolytic process journal December 1989
Sputter deposition and characterization of Cd2SnO4 films journal November 1978
Cd2SnO4 thin films obtained by d.c. reactive sputtering of Cd-Sn alloys journal February 1983
Solution‐Grown Cadmium Sulfide Films for Photovoltaic Devices journal September 1992
Cadmium‐tin oxide films deposited by rf sputtering from a CdO‐SnO 2 target journal October 1979
Properties of cadmium stannate films prepared by r.f. sputtering from powder targets journal February 1977
Transparent electrode properties of CdSn oxide films by dc reactive sputtering journal July 1979
Properties of two-phase cadmium stannate thin films journal February 1990
Cadmium stannate thin film as a solar energy utilizing element journal October 1993
CdS ‐ Cu2 S  Solar Cells Fabricated on Cd2SnO4 ‐ Silica Substrates journal November 1976
Deposition of transparent heat-reflecting coatings of metal oxides using reactive planar magnetron sputtering of a metal and/or alloy journal March 1981