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Title: Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof

Abstract

A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.

Inventors:
 [1];  [2];  [2]
  1. (Orinda, CA)
  2. (Corning, NY)
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA
OSTI Identifier:
873443
Patent Number(s):
US 6160158
Application Number:
09/026473
Assignee:
Regents of University of California (Oakland, CA) LBNL
DOE Contract Number:  
AC03-76SF00098
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
fluorination; utilizing; thermodynamically; unstable; fluorides; fluoride; salts; method; fluorinating; carbon; compound; cationic; utilizes; agent; selected; nickel; liquid; anhydrous; hydrogen; desired; organic; undergo; reacted; contacting; chosen; reaction; vessel; time; period; temperature; thermodynamically unstable; organic compound; time period; reaction vessel; fluoride salt; agent selected; carbon compound; reaction time; hydrogen fluoride; nickel fluoride; nickel fluorides; anhydrous hydrogen; /999/

Citation Formats

Bartlett, Neil, Whalen, J. Marc, and Chacon, Lisa. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof. United States: N. p., 2000. Web.
Bartlett, Neil, Whalen, J. Marc, & Chacon, Lisa. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof. United States.
Bartlett, Neil, Whalen, J. Marc, and Chacon, Lisa. Tue . "Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof". United States. https://www.osti.gov/servlets/purl/873443.
@article{osti_873443,
title = {Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof},
author = {Bartlett, Neil and Whalen, J. Marc and Chacon, Lisa},
abstractNote = {A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {12}
}

Patent:

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