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Selective thermal oxidation of hydrocarbons in zeolites by oxygen

Patent ·
OSTI ID:873392
 [1];  [2];  [3]
  1. Berkeley, CA
  2. Basel, CH
  3. Saint Charles, MO
+ Show Author Affiliations
A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.
Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA
DOE Contract Number:
AC03-76SF00098
Assignee:
Regents of University of California (Oakland, CA)
Patent Number(s):
US 6150562
OSTI ID:
873392
Country of Publication:
United States
Language:
English

References (5)

Selective Photooxidation of Small Alkenes by O2 with Red Light in Zeolite Y journal March 1994
Diffuse Reflectance Spectroscopy of Visible Alkene.O2 Charge-Transfer Absorptions in Zeolite Y and Determination of Photooxygenation Quantum Efficiencies journal December 1994
Very strong stabilization of alkene.cntdot.O2 charge-transfer state in zeolite NaY: red-light-induced photooxidation of 2,3-dimethyl-2-butene journal August 1993
Selective Oxidation of Toluene to Benzaldehyde by O2 with Visible Light in Barium(2+)- and Calcium(2+)-Exchanged Zeolite Y journal August 1994
Electron- and charge-transfer reactions within zeolites journal January 1993

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Related Subjects

/999/204/210/
adsorbed
alkanes
alkenes
alkyl
alkyl substituted
aromatics
byproducts
carried
completely
conditions
cycloalkyls
dark
free
highly
highly selective
hydrocarbons
hydrocarbons adsorbed
matrices
oxidation
oxidizes
oxygen
process
process oxidizes
production
selective
selective thermal
selectively
solvent
substantial
substituted
substituted alkanes
thermal
thermal conditions
thermal oxidation
unsubstituted
zeolite
zeolite matrices
zeolites