Selective thermal oxidation of hydrocarbons in zeolites by oxygen
Abstract
A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.
- Inventors:
-
- Berkeley, CA
- Basel, CH
- Saint Charles, MO
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- OSTI Identifier:
- 873392
- Patent Number(s):
- US 6150562
- Assignee:
- Regents of University of California (Oakland, CA)
- DOE Contract Number:
- AC03-76SF00098
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- selective; thermal; oxidation; hydrocarbons; zeolites; oxygen; process; adsorbed; zeolite; matrices; highly; unsubstituted; alkyl; substituted; alkanes; alkenes; aromatics; cycloalkyls; carried; solvent; free; dark; conditions; oxidizes; completely; selectively; substantial; production; byproducts; selective thermal; alkyl substituted; thermal oxidation; highly selective; thermal conditions; process oxidizes; substituted alkanes; zeolite matrices; hydrocarbons adsorbed; /999/204/210/
Citation Formats
Frei, Heinz, Blatter, Fritz, and Sun, Hai. Selective thermal oxidation of hydrocarbons in zeolites by oxygen. United States: N. p., 2000.
Web.
Frei, Heinz, Blatter, Fritz, & Sun, Hai. Selective thermal oxidation of hydrocarbons in zeolites by oxygen. United States.
Frei, Heinz, Blatter, Fritz, and Sun, Hai. Sat .
"Selective thermal oxidation of hydrocarbons in zeolites by oxygen". United States. https://www.osti.gov/servlets/purl/873392.
@article{osti_873392,
title = {Selective thermal oxidation of hydrocarbons in zeolites by oxygen},
author = {Frei, Heinz and Blatter, Fritz and Sun, Hai},
abstractNote = {A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.},
doi = {},
url = {https://www.osti.gov/biblio/873392},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {1}
}
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Works referenced in this record:
Very strong stabilization of alkene.cntdot.O2 charge-transfer state in zeolite NaY: red-light-induced photooxidation of 2,3-dimethyl-2-butene
journal, August 1993
- Blatter, Fritz; Frei, Heinz
- Journal of the American Chemical Society, Vol. 115, Issue 16
Very strong stabilization of alkene.cntdot.O2 charge-transfer state in zeolite NaY: red-light-induced photooxidation of 2,3-dimethyl-2-butene
journal, August 1993
- Blatter, Fritz; Frei, Heinz
- Journal of the American Chemical Society, Vol. 115, Issue 16
Selective Photooxidation of Small Alkenes by O2 with Red Light in Zeolite Y
journal, March 1994
- Blatter, Fritz; Frei, Heinz
- Journal of the American Chemical Society, Vol. 116, Issue 5
Selective Photooxidation of Small Alkenes by O2 with Red Light in Zeolite Y
journal, March 1994
- Blatter, Fritz; Frei, Heinz
- Journal of the American Chemical Society, Vol. 116, Issue 5
Diffuse Reflectance Spectroscopy of Visible Alkene.O2 Charge-Transfer Absorptions in Zeolite Y and Determination of Photooxygenation Quantum Efficiencies
journal, December 1994
- Blatter, Fritz; Moreau, Frederick; Frei, Heinz
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Diffuse Reflectance Spectroscopy of Visible Alkene.O2 Charge-Transfer Absorptions in Zeolite Y and Determination of Photooxygenation Quantum Efficiencies
journal, December 1994
- Blatter, Fritz; Moreau, Frederick; Frei, Heinz
- The Journal of Physical Chemistry, Vol. 98, Issue 50
Electron- and charge-transfer reactions within zeolites
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Electron- and charge-transfer reactions within zeolites
journal, January 1993
- Yoon, Kyung Byung
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Selective Oxidation of Toluene to Benzaldehyde by O2 with Visible Light in Barium(2+)- and Calcium(2+)-Exchanged Zeolite Y
journal, August 1994
- Sun, Hai; Blatter, Fritz; Frei, Heinz
- Journal of the American Chemical Society, Vol. 116, Issue 17
Selective Oxidation of Toluene to Benzaldehyde by O2 with Visible Light in Barium(2+)- and Calcium(2+)-Exchanged Zeolite Y
journal, August 1994
- Sun, Hai; Blatter, Fritz; Frei, Heinz
- Journal of the American Chemical Society, Vol. 116, Issue 17