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Title: Selective thermal oxidation of hydrocarbons in zeolites by oxygen

Abstract

A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Inventors:
 [1];  [2];  [3]
  1. Berkeley, CA
  2. Basel, CH
  3. Saint Charles, MO
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
OSTI Identifier:
873392
Patent Number(s):
US 6150562
Assignee:
Regents of University of California (Oakland, CA)
DOE Contract Number:  
AC03-76SF00098
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
selective; thermal; oxidation; hydrocarbons; zeolites; oxygen; process; adsorbed; zeolite; matrices; highly; unsubstituted; alkyl; substituted; alkanes; alkenes; aromatics; cycloalkyls; carried; solvent; free; dark; conditions; oxidizes; completely; selectively; substantial; production; byproducts; selective thermal; alkyl substituted; thermal oxidation; highly selective; thermal conditions; process oxidizes; substituted alkanes; zeolite matrices; hydrocarbons adsorbed; /999/204/210/

Citation Formats

Frei, Heinz, Blatter, Fritz, and Sun, Hai. Selective thermal oxidation of hydrocarbons in zeolites by oxygen. United States: N. p., 2000. Web.
Frei, Heinz, Blatter, Fritz, & Sun, Hai. Selective thermal oxidation of hydrocarbons in zeolites by oxygen. United States.
Frei, Heinz, Blatter, Fritz, and Sun, Hai. Sat . "Selective thermal oxidation of hydrocarbons in zeolites by oxygen". United States. https://www.osti.gov/servlets/purl/873392.
@article{osti_873392,
title = {Selective thermal oxidation of hydrocarbons in zeolites by oxygen},
author = {Frei, Heinz and Blatter, Fritz and Sun, Hai},
abstractNote = {A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.},
doi = {},
url = {https://www.osti.gov/biblio/873392}, journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {1}
}

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Works referenced in this record:

Selective Photooxidation of Small Alkenes by O2 with Red Light in Zeolite Y
journal, March 1994


Selective Photooxidation of Small Alkenes by O2 with Red Light in Zeolite Y
journal, March 1994


Diffuse Reflectance Spectroscopy of Visible Alkene.O2 Charge-Transfer Absorptions in Zeolite Y and Determination of Photooxygenation Quantum Efficiencies
journal, December 1994


Diffuse Reflectance Spectroscopy of Visible Alkene.O2 Charge-Transfer Absorptions in Zeolite Y and Determination of Photooxygenation Quantum Efficiencies
journal, December 1994


Electron- and charge-transfer reactions within zeolites
journal, January 1993


Electron- and charge-transfer reactions within zeolites
journal, January 1993


Selective Oxidation of Toluene to Benzaldehyde by O2 with Visible Light in Barium(2+)- and Calcium(2+)-Exchanged Zeolite Y
journal, August 1994


Selective Oxidation of Toluene to Benzaldehyde by O2 with Visible Light in Barium(2+)- and Calcium(2+)-Exchanged Zeolite Y
journal, August 1994