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Title: High temperature thermometric phosphors for use in a temperature sensor

Patent ·
OSTI ID:871428

A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.(y), wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
DOE Contract Number:
AC05-84OR21400
Assignee:
Lockheed Martin Energy Systems, Inc. (Oak Ridge, TN)
Patent Number(s):
US 5730528
OSTI ID:
871428
Country of Publication:
United States
Language:
English

References (5)

Lanthanide Orthophosphates as a Matrix for Solidified Radioactive Defense and Reactor Wastes journal January 1981
Characterization of high-temperature thermographic phosphors: spectral properties of LuPO_4:Dy(1%),Eu(2%) journal January 1995
Emission properties of europium-doped lanthanum and lutetium orthophosphate crystals for use in high temperature sensor applications conference January 1989
Raman spectra of the rare earth orthophosphates journal August 1981
The observation by EPR of trivalent hafnium in LuPO 4 , YPO 4 , and ScPO 4 journal September 1985