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Method for the photocatalytic conversion of methane

Patent ·
OSTI ID:871381
A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time.
Research Organization:
Pittsburgh Energy Technology Center
Assignee:
United States of America as represented by United States (Washington, DC)
Patent Number(s):
US 5720858
OSTI ID:
871381
Country of Publication:
United States
Language:
English

References (11)

Factors influencing the photocatalytic efficiency of WO3 particles journal September 1989
Photocatalytic hydrogen production with semiconductor particulate systems: An effort to enhance the efficiency journal January 1991
Preparation and characterization of doped WO3 photocatalyst powders journal June 1989
Hydrogen production with visible light using metal loaded-WO3 and MV2+ in aqueous medium journal January 1989
Doping effects of transition metal ions on the photosensitization of WO3 particles journal October 1988
Visible light induced water cleavage in colloidal solutions of chromium-doped titanium dioxide particles journal June 1982
Electron transfer reactions and flat-band potentials of tungsten(VI) oxide colloids journal November 1984
Visible light induced hydrogen production with Cu(II)/Bi2O3 and Pt/Bi2O3/RuO2 from aqueous methyl viologen solution journal January 1993
Hydrogen generation using Cu(II)/WO3 and oxalic acid by visible light journal January 1988
Photochemical conversion of methane journal January 1988
Hydrogen evolution from water with visible radiation in presence of Cu(II)/WO3 and electron relay journal January 1989