Metal regeneration of iron chelates in nitric oxide scrubbing
Patent
·
OSTI ID:871100
- El Cerrito, CA
- Oakland, CA
- Berkeley, CA
The present invention relates to a process of using metal particles to reduce NO to NH.sub.3. More specifically, the invention concerns an improved process to regenerate iron (II) (CHELATE) by reduction of iron (II) (CHELATE) (NO) complex, which process comprises: a) contacting an aqueous solution containing iron (II) (CHELATE) (NO) with metal particles at between about 20.degree. and 90.degree. C. to reduce NO present, produce ammonia or an ammonium ion, and produce free iron (II) (CHELATE) at a pH of between about 3 and 8. The process is useful to remove NO from flue gas and reduce pollution.
- Research Organization:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA
- Sponsoring Organization:
- United States Department of Energy
- DOE Contract Number:
- AC03-76SF00098
- Assignee:
- Regents of California (Oakland, CA)
- Patent Number(s):
- US 5658545
- OSTI ID:
- 871100
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
/423/
20
90
ammonia
ammonium
aqueous
aqueous solution
chelate
chelates
complex
comprises
concerns
contacting
containing
containing iron
degree
flue
flue gas
free
gas
ii
improved
improved process
iron
iron chelate
metal
metal particle
metal particles
nh
nitric
nitric oxide
oxide
particles
ph
pollution
process
process comprises
produce
reduce
reduction
regenerate
regeneration
relates
remove
scrubbing
solution
solution containing
specifically
useful
20
90
ammonia
ammonium
aqueous
aqueous solution
chelate
chelates
complex
comprises
concerns
contacting
containing
containing iron
degree
flue
flue gas
free
gas
ii
improved
improved process
iron
iron chelate
metal
metal particle
metal particles
nh
nitric
nitric oxide
oxide
particles
ph
pollution
process
process comprises
produce
reduce
reduction
regenerate
regeneration
relates
remove
scrubbing
solution
solution containing
specifically
useful