Halogenation of cobalt dicarbollide

Hurlburt, Paul K; Abney, Kent D; Kinkead, Scott A

Halogenation of cobalt dicarbollide

Patent · Tue Dec 31 23:00:00 EST 1996

OSTI ID:870958

Hurlburt, Paul K ^[1]; Abney, Kent D ^[1]; Kinkead, Scott A ^[1]

Los Alamos, NM

A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10' positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron.

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM

DOE Contract Number:: W-7405-ENG-36

Assignee:: Regents of University of California (Alameda, CA)

Patent Number(s):: US 5631390

OSTI ID:: 870958

Country of Publication:: United States

Language:: English

References (6)

B-Halogen derivatives of the bis(1,2-dicarbollyl)cobalt(III) anion Mátel, Ľ.; Macášek, F.; Rajec, P. Polyhedron, Vol. 1, Issue 6 https://doi.org/10.1016/S0277-5387(00)81604-6	journal	January 1982
New weakly coordinating anions. 2. Derivatization of the carborane anion CB11H12- Jelinek, Tomas; Baldwin, Patricia; Scheidt, W. Robert Inorganic Chemistry, Vol. 32, Issue 10 https://doi.org/10.1021/ic00062a018	journal	May 1993
Reconstruction of the 1,2-dicarbaclovododecaborane(12) structure by boron-atom insertion with (3)-1,2-dicarbollide ions Hawthorne, M. Frederick; Wegner, Patrick A. Journal of the American Chemical Society, Vol. 90, Issue 4 https://doi.org/10.1021/ja01006a009	journal	February 1968
.pi.-Dicarbollyl derivatives of the transition metals. Metallocene analogs Hawthorne, M. Frederick; Young, Donald Clifford; Andrews, Timothy D. Journal of the American Chemical Society, Vol. 90, Issue 4 https://doi.org/10.1021/ja01006a008	journal	February 1968
Effects of amine-borane structure on the stoichiometry, rate and mechanism of reaction with hypochlorous acid: hydride oxidation versus B-chlorination Bell, Kevin E.; Kelly, Curtis R.; Minter, David E. Inorganica Chimica Acta, Vol. 211, Issue 2 https://doi.org/10.1016/S0020-1693(00)85601-7	journal	September 1993
Preparation and characterization of the (3)-1,2- and (3)-1,7-dicarbadodecahydroundecaborate(-1) ions Hawthorne, M. Frederick; Young, Donald Clifford; Garrett, Philip M. Journal of the American Chemical Society, Vol. 90, Issue 4 https://doi.org/10.1021/ja01006a006	journal	February 1968

Similar Records

Halogenation of cobalt dicarbollide

Patent · Tue May 20 00:00:00 EDT 1997 · OSTI ID:489090

Preparation and use of tetra-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents

Patent · Tue Dec 31 23:00:00 EST 1996 · OSTI ID:870833

Preparation and use of tetra-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents

Patent · Mon Feb 10 23:00:00 EST 1997 · OSTI ID:441859

Related Subjects

/999/
acid
added
adding
anion
anions
b10
bromine
chlorine
cobalt
cobalt dicarbollide
dicarbollide
electrophilic
gaseous
halogenation
halogens
hypohalous
involves
iodine
iron
means
method
n-halosuccinimide
positions
presence
process
process involves
reactions
selectively
substitution
substitution reaction
substitution reactions

Halogenation of cobalt dicarbollide

Citation Formats

References (6)

Similar Records

Related Subjects