Process for recovering pertechnetate ions from an aqueous solution also containing other ions

Rogers, Robin; Horwitz, E Philip; Bond, Andrew H

Process for recovering pertechnetate ions from an aqueous solution also containing other ions

Patent · Tue Dec 31 23:00:00 EST 1996

OSTI ID:870837

Rogers, Robin ^[1]; Horwitz, E Philip ^[2]; Bond, Andrew H ^[3]

DeKalb, IL
Naperville, IL
Tallahassee, FL

A solid/liquid process for the separation and recovery of TcO.sub.4.sup.-1 ions from an aqueous solution is disclosed. The solid support comprises separation particles having surface-bonded poly(ethylene glycol) groups; whereas the aqueous solution from which the TcO.sub.4.sup.-1 ions are separated contains a poly(ethylene glycol) liquid/liquid biphase-forming amount of a dissolved salt. A solid/liquid phase admixture of separation particles containing bound TcO.sub.4.sup.-1 ions in such an aqueous solution that is free from MoO.sub.4.sup.-2 ions is also contemplated, as is a chromatography apparatus containing that solid/liquid phase admixture.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL

DOE Contract Number:: W-31109-ENG-38

Assignee:: Arch Development Corp. (Chicago, IL); Board of Regents for Northern Illinois University (DeKalb, IL)

Patent Number(s):: US 5603834

OSTI ID:: 870837

Country of Publication:: United States

Language:: English

References (14)

Metal-ion complexation of noncyclic poly(oxyethylene) derivatives. 6. Solid-solid-liquid three phase transfer catalysis of polymer-bound acyclic poly(oxyethylene) derivatives. Applications to organic synthesis Yanagida, Shozo; Takahashi, Kazutomo; Okahara, Mitsuo The Journal of Organic Chemistry, Vol. 44, Issue 7 https://doi.org/10.1021/jo01321a015	journal	March 1979
Non-supported and resin-supported oligo(oxyethylenes) as solid–liquid phase-transfer catalysts. Effect of chain length and head-group Heffernan, James G.; MacKenzie, William M.; Sherrington, David C. J. Chem. Soc., Perkin Trans. 2, Issue 3 https://doi.org/10.1039/P29810000514	journal	January 1981
Technetium Radiopharmaceuticals—Fundamentals, Synthesis, Structure, and Development Schwochau, Klaus Angewandte Chemie International Edition in English, Vol. 33, Issue 22 https://doi.org/10.1002/anie.199422581	journal	December 1994
Polyether-based triphase catalysts. A synthetic comparison Fukunishi, Koji; Czech, Bronislaw; Regen, Steven L. The Journal of Organic Chemistry, Vol. 46, Issue 6 https://doi.org/10.1021/jo00319a039	journal	March 1981
Polystyrene-Immobilized PEG Chains Bayer, Ernst; Rapp, Wolfgang Poly(Ethylene Glycol) Chemistry https://doi.org/10.1007/978-1-4899-0703-5_20	book	January 1992
Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K Marcus, Yizhak J. Chem. Soc., Faraday Trans., Vol. 87, Issue 18 https://doi.org/10.1039/FT9918702995	journal	January 1991
Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane Regen, Steven L.; Besse, Jacques J.; McLick, Jerome Journal of the American Chemical Society, Vol. 101, Issue 1 https://doi.org/10.1021/ja00495a019	journal	January 1979
Surface affinity chromatographic separation of blood cells Matsumoto, Ushiho; Shibusawa, Yōichi; Tanaka, Yō Journal of Chromatography A, Vol. 268 https://doi.org/10.1016/S0021-9673(01)95436-6	journal	January 1983
Surface affinity chromatographic separation of blood cells Matsumoto, Ushiho; Shibusawa, Yōichi Journal of Chromatography A, Vol. 187, Issue 2 https://doi.org/10.1016/S0021-9673(00)80467-7	journal	January 1980
Poly(ethylene glycols) and poly(ethylene glycol)-grafted copolymers are extraordinary catalysts for dehydrohalogenation under two-phase and three-phase conditions Kimura, Yoshikazu; Regen, Steven L. The Journal of Organic Chemistry, Vol. 48, Issue 2 https://doi.org/10.1021/jo00150a011	journal	January 1983
Polyurethane foams as selective sorbents for noble metals Jones, Lynn; Nel, Iris; Koch, Klaus R. Analytica Chimica Acta, Vol. 182 https://doi.org/10.1016/S0003-2670(00)82437-X	journal	January 1986
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Surface affinity chromatographic separation of blood cells Matsumoto, Ushiho; Ban, Midori; Shibusawa, Yōichi Journal of Chromatography A, Vol. 285 https://doi.org/10.1016/S0021-9673(01)87736-0	journal	January 1984

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biphase-forming amount
bound
chromatography
comprises
comprises separation
containing
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dissolved
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tco

Process for recovering pertechnetate ions from an aqueous solution also containing other ions

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References (14)

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