Ignitable heterogeneous stratified structure for the propagation of an internal exothermic chemical reaction along an expanding wavefront and method of making same
Patent
·
OSTI ID:870523
- Menlo Park, CA
A multilayer structure has a selectable, (i) propagating reaction front velocity V, (ii) reaction initiation temperature attained by application of external energy and (iii) amount of energy delivered by a reaction of alternating unreacted layers of the multilayer structure. Because V is selectable and controllable, a variety of different applications for the multilayer structures are possible, including but not limited to their use as ignitors, in joining applications, in fabrication of new materials, as smart materials and in medical applications and devices. The multilayer structure has a period D, and an energy release rate constant K. Two or more alternating unreacted layers are made of different materials and separated by reacted zones. The period D is equal to a sum of the widths of each single alternating reaction layer of a particular material, and also includes a sum of reacted zone widths, t.sub.i, in the period D. The multilayer structure has a selectable propagating reaction front velocity V, where V=K(1/D.sup.n).times.[1-(t.sub.i /D)] and n is about 0.8 to 1.2.
- Research Organization:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA
- DOE Contract Number:
- W-7405-ENG-48
- Assignee:
- Regents of University of California (Oakland, CA)
- Patent Number(s):
- US 5538795
- OSTI ID:
- 870523
- Country of Publication:
- United States
- Language:
- English
The propagation of a solid‐state combustion wave in Ni‐Al foils
|
journal | November 1989 |
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alternating
amount
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chemical
chemical reaction
constant
controllable
delivered
devices
energy
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equal
exothermic
expanding
external
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fabrication
front
front velocity
heterogeneous
heterogeneous stratified
ignitable
ignitable heterogeneous
ignitors
ii
iii
including
initiation
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internal
joining
layer
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limited
material
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medical
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method
multilayer
multilayer structure
multilayer structures
particular
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period
propagating
propagating reaction
propagation
rate
rate constant
reacted
reaction
reaction front
reaction initiation
reaction layer
release
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selectable
separated
single
smart
stratified
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temperature
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times
unreacted
variety
velocity
wavefront
widths
zone
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1-
alternating
amount
application
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constant
controllable
delivered
devices
energy
energy release
equal
exothermic
expanding
external
external energy
fabrication
front
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heterogeneous
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ignitable
ignitable heterogeneous
ignitors
ii
iii
including
initiation
initiation temperature
internal
joining
layer
layers
limited
material
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medical
medical applications
method
multilayer
multilayer structure
multilayer structures
particular
particular material
period
propagating
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rate
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reacted
reaction
reaction front
reaction initiation
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single
smart
stratified
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temperature
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times
unreacted
variety
velocity
wavefront
widths
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