Synthesis of BiPbSrCaCuO superconductor

Patent · Sat Jan 01 00:00:00 EST 1994

OSTI ID:869224

Hults, William L ^[1]; Kubat-Martin, Kimberly A ^[2]; Salazar, Kenneth V ^[2]; Phillips, David S ^[1]; Peterson, Dean E ^[1]

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1. Los Alamos, NM
2. Espanola, NM

A process and a precursor composition for preparing a lead-doped bismuth-strontium-calcium-copper oxide superconductor of the formula Bi.sub.a Pb.sub.b Sr.sub.c Ca.sub.d Cu.sub.e O.sub.f wherein a is from about 1.7 to about 1.9, b is from about 0.3 to about 0.45, c is from about 1.6 to about 2.2, d is from about 1.6 to about 2.2, e is from about 2.97 to about 3.2 and f is 10.+-.z by reacting a mixture of Bi.sub.4 Sr.sub.3 Ca.sub.3 Cu.sub.4 O.sub.16.+-.z, an alkaline earth metal cuprate, e.g., Sr.sub.9 Ca.sub.5 Cu.sub.24 O.sub.41, and an alkaline earth metal plumbate, e.g., Ca.sub.2-x Sr.sub.x PbO.sub.4 wherein x is about 0.5, is disclosed.

• Research Organization: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
• DOE Contract Number: W-7405-ENG-36
• Assignee: United States of America as represented by United States (Washington, DC)
• Patent Number(s): US 5300486
• OSTI ID: 869224
• Country of Publication: United States
• Language: English

Related Subjects

synthesis
bipbsrcacuo
superconductor
process
precursor
composition
preparing
lead-doped
bismuth-strontium-calcium-copper
oxide
formula
pb
sr
cu
45
97
10
z
reacting
mixture
16
alkaline
earth
metal
cuprate
24
41
plumbate
2-x
pbo
disclosed
copper oxide
alkaline earth
earth metal
oxide superconductor
/505/423/