Synthetic route to meso-tetra hydrocarbyl or substituted hydrocarbyl porphyrins and derivatives

Wijesekera, Tilak P; Wagner, Richard W

Synthetic route to meso-tetra hydrocarbyl or substituted hydrocarbyl porphyrins and derivatives

Patent · Thu Dec 31 23:00:00 EST 1992

OSTI ID:868906

Wijesekera, Tilak P ^[1]; Wagner, Richard W ^[2]

Glen Mills, PA
Murrysville, PA

The hydroxyl group in a pyrrolic compound having in the 2-position thereof a group having the formula R(OH)CH--R is hydrocarbyl or substituted hydrocarbyl, is replaced by a group, for example a p-nitrobenzoate group, having better leaving properties than those of hydroxyl for a subsequent self-condensation and cyclization of the pyrrolic compound to form a meso-hydrocarbyl or meso-substituted hydrocarbyl porphyrin.

Research Organization:: Sun Refining and Marketing Co., Marcus Hook, PA (United States)

DOE Contract Number:: FC21-90MC26029

Assignee:: Sun Company, Inc. (R&M) (Philadelphia, PA)

Patent Number(s):: US 5241062

OSTI ID:: 868906

Country of Publication:: United States

Language:: English

References (10)

Perhalogenated tetraphenylhemins: stable catalysts of high turnover catalytic hydroxylations Traylor, Teddy G.; Tsuchiya, Shinji Inorganic Chemistry, Vol. 26, Issue 8 https://doi.org/10.1021/ic00255a028	journal	April 1987
Formation and reactivity of 1-pyrrolyl-2,2,2-trifluoroethyl cations Allen, Annette D.; Kwong-Chip, Jean-Marc; Lin, Wing Cheung Canadian Journal of Chemistry, Vol. 68, Issue 10 https://doi.org/10.1139/v90-265	journal	October 1990
Investigation of the synthesis of ortho-substituted tetraphenylporphyrins Lindsey, Jonathan S.; Wagner, Richard W. The Journal of Organic Chemistry, Vol. 54, Issue 4 https://doi.org/10.1021/jo00265a021	journal	February 1989
On the preparation of metalloporphyrins Adler, Alan D.; Longo, Frederick R.; Kampas, Frank Journal of Inorganic and Nuclear Chemistry, Vol. 32, Issue 7 https://doi.org/10.1016/0022-1902(70)80535-8	journal	July 1970
Halogen substituent effects on the catalytic activity of iron porphyrin complexes for selective air-oxidation of alkanes in the liquid phase Ellis, Paul E.; Lyons, James E. Catalysis Letters, Vol. 3, Issue 5-6 https://doi.org/10.1007/BF00771267	journal	September 1989
Benzoylierungen in der Pyrrol-Reihe, II1) Treibs, Alfred; Jacob, Karl Justus Liebigs Annalen der Chemie, Vol. 733, Issue 1, p. 27-36 https://doi.org/10.1002/jlac.19707330104	journal	January 1970
Porphyrins. VII. The synthesis of porphyrins by the Rothemund reaction Badger, Gm; Jones, Ra; Laslett, Rl Australian Journal of Chemistry, Vol. 17, Issue 9 https://doi.org/10.1071/CH9641028	journal	January 1964
Selective low temperature hydroxylation of isobutane by molecular oxygen catalyzed by an iron perhaloporphyrin complex Lyons, James E.; Ellis, Paul E. Catalysis Letters, Vol. 8, Issue 1 https://doi.org/10.1007/BF00764382	journal	January 1991
Novel Synthetic Method of Phenol from Benzene Catalysed by Perfluorinated Hemin Tsuchiya, Shinji; Seno, Manabu Chemistry Letters, Vol. 18, Issue 2 https://doi.org/10.1246/cl.1989.263	journal	February 1989
A new route for meso-substituted porphyrin Kuroda, Yasuhisa; Murase, auHiroaki; Suzuki, Yasuhiko Tetrahedron Letters, Vol. 30, Issue 18 https://doi.org/10.1016/S0040-4039(01)80413-5	journal	January 1989

Similar Records

Synthetic route to meso-tetra hydrocarbyl or substituted hydrocarbyl porphyrins and derivatives

Patent · Tue Aug 31 00:00:00 EDT 1993 · OSTI ID:6047121

Preparation of porphyrins and their metal complexes

Patent · Tue Aug 19 00:00:00 EDT 1997 · OSTI ID:527766

Preparation of porphyrins and their metal complexes

Patent · Tue Dec 31 23:00:00 EST 1996 · OSTI ID:871104

Related Subjects

/999/
2-position
ch--r
compound
cyclization
derivatives
example
form
formula
hydrocarbyl
hydroxyl
leaving
meso-hydrocarbyl
meso-substituted
meso-tetra
oh
p-nitrobenzoate
porphyrin
porphyrins
properties
pyrrolic
pyrrolic compound
replaced
route
self-condensation
subsequent
substituted
substituted hydrocarbyl
synthetic

Synthetic route to meso-tetra hydrocarbyl or substituted hydrocarbyl porphyrins and derivatives

Citation Formats

References (10)

Similar Records

Related Subjects