Low density, resorcinol-formaldehyde aerogels
Patent
·
OSTI ID:867129
- Pleasant Hill, CA
The polycondensation of resorcinol with formaldehyde under alkaline conditions results in the formation of surface functionalized polymer "clusters". The covalent crosslinking of these "clusters" produces gels which when processed under supercritical conditions, produce low density, organic aerogels (density .ltoreq.100 mg/cc; cell size .ltoreq.0.1 microns). The aerogels are transparent, dark red in color and consist of interconnected colloidal-like particles with diameters of about 100 .ANG.. These aerogels may be further carbonized to form low density carbon foams with cell size of about 0.1 micron.
- Research Organization:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA
- DOE Contract Number:
- W-7405-ENG-48
- Assignee:
- United States Department of Energy (WA)
- Patent Number(s):
- US 4873218
- OSTI ID:
- 867129
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
/502/521/
100
aerogels
alkaline
alkaline condition
alkaline conditions
ang
carbon
carbon foam
carbon foams
carbonized
cc
cell
cell size
clusters
colloidal-like
color
conditions
conditions results
consist
covalent
covalent crosslinking
crosslinking
dark
density
density carbon
diameters
foams
form
formaldehyde
formation
functionalized
functionalized polymer
gels
interconnected
ltoreq
mg
micron
microns
organic
organic aerogel
organic aerogels
particles
polycondensation
polymer
processed
produce
produces
produces gels
resorcinol
resorcinol-formaldehyde
resorcinol-formaldehyde aerogels
results
size
supercritical
supercritical conditions
surface
surface functional
surface functionalized
transparent
100
aerogels
alkaline
alkaline condition
alkaline conditions
ang
carbon
carbon foam
carbon foams
carbonized
cc
cell
cell size
clusters
colloidal-like
color
conditions
conditions results
consist
covalent
covalent crosslinking
crosslinking
dark
density
density carbon
diameters
foams
form
formaldehyde
formation
functionalized
functionalized polymer
gels
interconnected
ltoreq
mg
micron
microns
organic
organic aerogel
organic aerogels
particles
polycondensation
polymer
processed
produce
produces
produces gels
resorcinol
resorcinol-formaldehyde
resorcinol-formaldehyde aerogels
results
size
supercritical
supercritical conditions
surface
surface functional
surface functionalized
transparent