Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate
Patent
·
OSTI ID:866864
- San Pablo, CA
- El Cerrito, CA
A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.
- Research Organization:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA
- DOE Contract Number:
- AC03-76SF00098
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Number(s):
- US 4810474
- OSTI ID:
- 866864
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
--n--a
/423/
alkyl
aqueous
aqueous solution
atmospheric
atoms
carbon
carbon atom
carbon atoms
chelate
compound
compound-iron
compounds
comprises
contacting
contacting zone
containing gas
effective
flue
flue gas
flue gases
formula
functional
gas
gases
hydrogen
ion-dithiocarbamate
iron
method
method comprise
method comprises
mixtures
moiety
monoxide
monoxide-containing
monoxide-containing gas
nitrogen
nitrogen monoxide
nitrogen monoxide-containing
nitrogen oxide
organic
organic compound
oxide-containing
oxide-containing gas
oxygen
polar
pollution
potassium
provide
reduce
reducing
removing
removing nitrogen
selected
sodium
soluble
soluble organic
solution
str1
str2
sulfur
temperature
temperature effective
thioxanthate
time
unexpensive
useful
water
water soluble
water-soluble
water-soluble organic
xanthate
z
zone
/423/
alkyl
aqueous
aqueous solution
atmospheric
atoms
carbon
carbon atom
carbon atoms
chelate
compound
compound-iron
compounds
comprises
contacting
contacting zone
containing gas
effective
flue
flue gas
flue gases
formula
functional
gas
gases
hydrogen
ion-dithiocarbamate
iron
method
method comprise
method comprises
mixtures
moiety
monoxide
monoxide-containing
monoxide-containing gas
nitrogen
nitrogen monoxide
nitrogen monoxide-containing
nitrogen oxide
organic
organic compound
oxide-containing
oxide-containing gas
oxygen
polar
pollution
potassium
provide
reduce
reducing
removing
removing nitrogen
selected
sodium
soluble
soluble organic
solution
str1
str2
sulfur
temperature
temperature effective
thioxanthate
time
unexpensive
useful
water
water soluble
water-soluble
water-soluble organic
xanthate
z
zone