Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers
- Bend, OR
Novel semiperimeable membranes and thin film composite (TFC) gas separation membranes useful in the separation of oxygen, nitrogen, hydrogen, water vapor, methane, carbon dioxide, hydrogen sulfide, lower hydrocarbons, and other gases are disclosed. The novel semipermeable membranes comprise the polycondensation reaction product of two complementary polyfunctional compounds, each having at least two functional groups that are mutually reactive in a condensation polymerization reaction, and at least one of which is selected from siloxanes, alkoxsilyls and aryloxysilyls. The TFC membrane comprises a microporous polymeric support, the surface of which has the novel semipermeable film formed thereon, preferably by interfacial polymerization.
- Research Organization:
- Bend Research Inc
- DOE Contract Number:
- AC03-84ER80159
- Assignee:
- Bend Research, Inc. (Bend, OR)
- Patent Number(s):
- US 4781733
- OSTI ID:
- 866760
- Country of Publication:
- United States
- Language:
- English
Similar Records
Siloxane-grafted membranes
Siloxane-grafted membranes
Related Subjects
alkoxsilyls
alkoxysilyl
aryloxysilyl
aryloxysilyls
carbon
carbon dioxide
complementary
composite
compounds
comprise
comprises
comprising
condensation
condensation polymerization
copolymers
dioxide
disclosed
film
film composite
film formed
film membranes
formed
formed thereon
functional
gas
gas separation
gases
hydrocarbons
hydrogen
hydrogen sulfide
interfacial
interfacial polymerization
membrane
membrane comprises
membranes
membranes comprising
membranes useful
methane
microporous
microporous polymer
microporous polymeric
mutually
nitrogen
novel
oligomers
oxygen
permeable membrane
permeable membranes
polycondensation
polyfunctional
polymeric
polymeric support
polymerization
polymerization reaction
porous polymer
preferably
product
reaction
reaction product
reactive
selected
semiperimeable
semipermeable
semipermeable membrane
semipermeable membranes
separation
separation membrane
separation membranes
siloxane
siloxanes
sulfide
support
surface
tfc
thereon
thin-film
useful
vapor
water
water vapor