Electrodeposition of magnesium and magnesium/aluminum alloys

Title: Electrodeposition of magnesium and magnesium/aluminum alloys

Full Record
Other Related Research

Abstract

Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

Inventors:

Mayer, Anton ^[1]

Los Alamos, NM

Publication Date:: 1988-01-01

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

OSTI Identifier:: 866743

Patent Number(s):: US 4778575

Assignee:: United States of America as represented by United States (Washington, DC)

DOE Contract Number:: W-7405-ENG-36

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: electrodeposition; magnesium; aluminum; alloys; electrolytes; plating; solutions; processes; electroplating; electroforming; pure; electrolyte; comprised; alkali; metal; fluoride; quaternary; ammonium; halide; dimethyl; diethyl; triethyl; triisobutyl; dissolved; aromatic; hydrocarbon; solvent; form; solution; proportions; component; compounds; varied; produce; essentially; varying; selected; compositions; plating solution; quaternary ammonium; alkali metal; deposition process; aluminum alloy; metal fluoride; aromatic hydrocarbon; deposition processes; aluminum alloys; hydrocarbon solvent; selected composition; essentially pure; plating solutions; /205/

Citation Formats


                    Mayer, Anton. Electrodeposition of magnesium and magnesium/aluminum alloys.  United States: N. p., 1988. 
        Web.

Copy to clipboard


                    Mayer, Anton. Electrodeposition of magnesium and magnesium/aluminum alloys.  United States.

Copy to clipboard


                    Mayer, Anton. Fri .  
        "Electrodeposition of magnesium and magnesium/aluminum alloys".  United States.  https://www.osti.gov/servlets/purl/866743.

Copy to clipboard


                    
@article{osti_866743,

  title        = {Electrodeposition of magnesium and magnesium/aluminum alloys},

  author       = {Mayer, Anton},

  abstractNote = {Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.},

  doi          = {},

  url          = {https://www.osti.gov/biblio/866743},
  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1988},

  month        = {1}

}

Copy to clipboard

Patent:

View Patent

Save / Share:

Export Metadata

Save to My Library

Similar records in OSTI.GOV collections:

Electrodeposition of magnesium and magnesium/aluminum alloys

Patent Mayer, A.

Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.
Full Text Available
Electrodeposition of magnesium and magnesium/aluminum alloys

Patent Mayer, A

Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/alumnum alloys having varying selected compositions.
Electrodeposition of aluminium, aluminium/magnesium alloys, and magnesium from organometallic electrolytes

Conference Mayer, A

The electrodeposition of aluminum, magnesium, and the combination of these metals from nonaqueous media is discussed. Plating baths for depositing Al/Mg alloys or for plating essentially pure Mg were developed. These solutions contain alkali meal fluoride or quaternary ammonium halide/aluminium alkyl complexes and dialkyl magnesium dissolved in aromatic hydrocarbons. Alloy deposits over the whole composition range can be plated from these solutions by varying the relative quantities of the aluminium and magnesium alkyls and by changing the bath-operating parameters. 18 refs., 4 figs.
Full Text Available
Chemistry and electrochemistry of molybdenum plating from molten salts

Technical Report White, S H ; Twardoch, U M

This paper is concerned with the synergism between solution chemistry and the electrode chemistry in electroplating molybdenum. Before presenting the results from some basic studies, this specific area of materials processing is placed in the context of electrolytic methods of materials fabrication for use in corrosive environments at elevated temperatures and high potentials. EIC has ongoing programs which are concerned with the development of electroplating refractory metals, in particular these in VIA, chromium, molybdenum, and tungsten from electrolyte operating below 500 C. These metals are of particular interest in view of their high melting points, hardness, and corrosion resistance, particularlymore »« less
ELECTRODEPOSITION OF ALUMINUM ON MAGNESIUM. Period covered: June 1, 1958 through March 31, 1959

Technical Report Cooke, E W ; Kritzer, S

Detailed tests made to electrodeposit aluminum directly onto magnesium, using a modification of the nonaqueous both developed by the National Bureau of Standards, are described. It is shown that good adhesion is not obtained sad a reaction occurs between the electroplating solution and magnesium. However, it is indicated that by using a zinc immersion intermediate coating, satisfactory adhesion is obtained. The purity of aluminum deposited in this manner is greater than 99.8%, with low porosity. Good adhesion is also obtained on copper and steel. These coatings can be satisfactorily anodized. (auth)

Similar Records