Superlattice photoelectrodes for photoelectrochemical cells
Patent
·
OSTI ID:866102
- Boulder, CO
A superlattice or multiple-quantum-well semiconductor is used as a photoelectrode in a photoelectrochemical process for converting solar energy into useful fuels or chemicals. The quantum minibands of the superlattice or multiple-quantum-well semiconductor effectively capture hot-charge carriers at or near their discrete quantum energies and deliver them to drive a chemical reaction in an electrolyte. The hot-charge carries can be injected into the electrolyte at or near the various discrete multiple energy levels quantum minibands, or they can be equilibrated among themselves to a hot-carrier pool and then injected into the electrolyte at one average energy that is higher than the lowest quantum band gap in the semiconductor.
- Research Organization:
- MIDWEST RESEARCH INSTITUTE
- DOE Contract Number:
- AC02-83CH10093
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Number(s):
- US 4634641
- OSTI ID:
- 866102
- Country of Publication:
- United States
- Language:
- English
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average
average energy
band
band gap
capture
carriers
carries
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charge carrier
charge carriers
chemical
chemical process
chemical reaction
chemicals
converting
converting solar
deliver
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electrochemical cell
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electrochemical process
electrolyte
energies
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energy level
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equilibrated
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hot-carrier
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minibands
multiple
multiple-quantum-well
near
photoelectrochemical
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photoelectrochemical cells
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photoelectrodes
pool
process
quantum
reaction
semiconductor
solar
solar energy
superlattice
useful
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average
average energy
band
band gap
capture
carriers
carries
cells
charge carrier
charge carriers
chemical
chemical process
chemical reaction
chemicals
converting
converting solar
deliver
discrete
drive
effectively
electrochemical cell
electrochemical cells
electrochemical process
electrolyte
energies
energy
energy level
energy levels
equilibrated
fuels
gap
hot-carrier
hot-charge
injected
levels
lowest
minibands
multiple
multiple-quantum-well
near
photoelectrochemical
photoelectrochemical cell
photoelectrochemical cells
photoelectrode
photoelectrodes
pool
process
quantum
reaction
semiconductor
solar
solar energy
superlattice
useful
various