Ethylenediamine salt of 5-nitrotetrazole and preparation
- Los Alamos, NM
Ethylenediamine salt of 5-nitrotetrazole and preparation. This salt has been found to be useful as an explosive alone and in eutectic mixtures with ammonium nitrate and/or other explosive compounds. Its eutectic with ammonium nitrate has been demonstrated to behave in a similar manner to a monomolecular explosive such as TNT, and is less sensitive than the pure salt. Moreover, this eutectic mixture, which contains 87.8 mol % of ammonium nitrate, is close to the CO.sub.2 -balanced composition of 90 mol %, and has a relatively low melting point of 110.5 C. making it readily castable. The ternary eutectic system containing the ethylenediamine salt of 5-nitrotetrazole, ammonium nitrate and ethylenediamine dinitrate has a eutectic temperature of 89.5 C. and gives a measured detonation pressure of 24.8 GPa, which is 97.6% of the calculated value. Both the pure ethylenediamine salt and its known eutectic compounds behave in substantially ideal manner. Methods for the preparation of the salt are described.
- Research Organization:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- DOE Contract Number:
- W-7405-ENG-36
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Number(s):
- US 4552598
- OSTI ID:
- 865664
- Country of Publication:
- United States
- Language:
- English
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salt
5-nitrotetrazole
preparation
found
useful
explosive
eutectic
mixtures
ammonium
nitrate
compounds
demonstrated
behave
similar
manner
monomolecular
tnt
sensitive
pure
moreover
mixture
contains
87
mol
close
-balanced
composition
90
relatively
melting
110
readily
castable
ternary
containing
dinitrate
temperature
89
measured
detonation
pressure
24
gpa
97
calculated
value
substantially
ideal
methods
described
ternary eutectic
ammonium nitrate
ethylenediamine dinitrate
ethylenediamine salt
eutectic temperature
eutectic mixture
explosive compound
explosive compounds
eutectic mixtures
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