Electrochemical cell
Patent
·
OSTI ID:864984
- New Lenox, IL
An improved secondary electrochemical cell is disclosed having a negative electrode of lithium aluminum, a positive electrode of iron sulfide, a molten electrolyte of lithium chloride and potassium chloride, and the combination that the fully charged theoretical capacity of the negative electrode is in the range of 0.5-1.0 that of the positive electrode. The cell thus is negative electrode limiting during discharge cycling. Preferably, the negative electrode contains therein, in the approximate range of 1-10 volume % of the electrode, an additive from the materials of graphitized carbon, aluminum-iron alloy, and/or magnesium oxide.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL
- DOE Contract Number:
- W-31109-ENG-38
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Number(s):
- US 4446212
- OSTI ID:
- 864984
- Country of Publication:
- United States
- Language:
- English
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/429/
1-10
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aluminum-iron
approximate
approximate range
capacity
carbon
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chloride
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electrochemical
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electrode contains
electrolyte
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magnesium
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potassium
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preferably
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secondary
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sulfide
theoretical
therein
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1-10
5-1
additive
alloy
aluminum
aluminum-iron
approximate
approximate range
capacity
carbon
cell
charged
chloride
combination
contains
cycling
discharge
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electrode
electrode contains
electrolyte
graphitized
graphitized carbon
improved
iron
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iron sulfide
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lithium
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magnesium
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negative
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oxide
positive
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potassium
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sulfide
theoretical
therein
volume