Method of boronizing transition metal surfaces
Patent
·
OSTI ID:864665
- Hyogo, JP
- Hinsdale, IL
A method is presented for preparing a boride layer on a transition metal substrate for use in corrosive environments or as a harden surface in machine applications. This method is particularly useful in treating current collectors for use within a high temperature and corrosive electrochemical cell environment. A melt of a alkali metal boride tetrafluoride salt including such as KF to lower its melting point is prepared including a dissolved boron containing material, for instance NiB, MnB.sub.2, or CrB.sub.2. A transition metal to be coated is immersed in the melt at a temperature of no more than 700.degree. C. and a surface boride layer of that transition metal is formed within a period of about 24 hours on the substrate surface.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL
- DOE Contract Number:
- W-31109-ENG-38
- Assignee:
- Koyama, Koichiro (Hyogo, JP);Shimotake, Hiroshi (Hinsdale, IL)
- Patent Number(s):
- US 4398968
- OSTI ID:
- 864665
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
/148/427/
24
700
alkali
alkali metal
applications
boride
boron
boron containing
boronizing
cell
cell environment
coated
collectors
containing
containing material
corrosive
corrosive environment
corrosive environments
crb
current
current collector
current collectors
degree
dissolved
electrochemical
electrochemical cell
environment
environments
fluoride salt
formed
harden
hours
immersed
including
instance
kf
layer
machine
material
melt
melting
metal
metal substrate
metal surface
metal surfaces
method
mnb
nib
particularly
particularly useful
period
prepared
preparing
salt
salt including
substrate
substrate surface
surface
surfaces
temperature
tetrafluoride
transition
transition metal
treating
useful
24
700
alkali
alkali metal
applications
boride
boron
boron containing
boronizing
cell
cell environment
coated
collectors
containing
containing material
corrosive
corrosive environment
corrosive environments
crb
current
current collector
current collectors
degree
dissolved
electrochemical
electrochemical cell
environment
environments
fluoride salt
formed
harden
hours
immersed
including
instance
kf
layer
machine
material
melt
melting
metal
metal substrate
metal surface
metal surfaces
method
mnb
nib
particularly
particularly useful
period
prepared
preparing
salt
salt including
substrate
substrate surface
surface
surfaces
temperature
tetrafluoride
transition
transition metal
treating
useful