Method of enhancing the wettability of boron nitride for use as an electrochemical cell separator
Patent
·
OSTI ID:864411
- Woodland Hills, CA
A felt or other fabric of boron nitride suitable for use as an interelecte separator within an electrochemical cell is wetted with a solution containing a thermally decomposable organic salt of an alkaline earth metal. An aqueous solution of magnesium acetate is the preferred solution for this purpose. After wetting the boron nitride, the solution is dried by heating at a sufficiently low temperature to prevent rapid boiling and the creation of voids within the separator. The dried material is then calcined at an elevated temperature in excess of 400.degree. C. to provide a coating of an oxide of magnesium on the surface of the boron nitride fibers. A fabric or felt of boron nitride treated in this manner is easily wetted by molten electrolytic salts, such as the alkali metal halides or alkaline earth metal halides, that are used in high temperature, secondary electrochemical cells.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL
- DOE Contract Number:
- W-31109-ENG-38
- Assignee:
- United States of America as represented by Department of Energy (Washington, DC)
- Patent Number(s):
- US 4360578
- OSTI ID:
- 864411
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
/429/427/
400
acetate
alkali
alkali metal
alkaline
alkaline earth
aqueous
aqueous solution
boiling
boron
boron nitride
calcined
cell
cell separator
cells
coating
containing
creation
decomposable
degree
dried
earth
earth metal
easily
electrochemical
electrochemical cell
electrochemical cells
electrolytic
electrolytic salt
elevated
elevated temperature
enhancing
excess
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halides
heating
interelecte
magnesium
manner
material
metal
metal halide
metal halides
method
molten
molten electrolytic
nitride
nitride fiber
organic
organic salt
oxide
preferred
prevent
provide
purpose
rapid
salt
salts
secondary
secondary electrochemical
separator
solution
solution containing
sufficiently
suitable
surface
temperature
thermally
thermally decomposable
treated
voids
wettability
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400
acetate
alkali
alkali metal
alkaline
alkaline earth
aqueous
aqueous solution
boiling
boron
boron nitride
calcined
cell
cell separator
cells
coating
containing
creation
decomposable
degree
dried
earth
earth metal
easily
electrochemical
electrochemical cell
electrochemical cells
electrolytic
electrolytic salt
elevated
elevated temperature
enhancing
excess
fabric
fibers
halides
heating
interelecte
magnesium
manner
material
metal
metal halide
metal halides
method
molten
molten electrolytic
nitride
nitride fiber
organic
organic salt
oxide
preferred
prevent
provide
purpose
rapid
salt
salts
secondary
secondary electrochemical
separator
solution
solution containing
sufficiently
suitable
surface
temperature
thermally
thermally decomposable
treated
voids
wettability
wetted
wetting