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Preparation of diamond-like carbon and boron nitirde films by high-intensity pulsed ion beam deposition

Conference ·
OSTI ID:83107
;  [1];  [2]
  1. Los Alamos National Lab., NM (United States)
  2. Tomsk Polytechnic Univ., Tomsk (Russian Federation). Nuclear Physics Institute.; and others

Intense ion beams (300-keV C{sup +}, O{sup +}, and H{sup +}, 20--30 kA, 50 to 400-ns pulsewidth, up to 0.3-Hz repetition rate) were used to prepare diamond-like carbon (DLC) and boron nitride (BN) films. Deposition rates of up to 25{plus_minus}5 nm/pulse were obtained with instantaneous rates exceeding 1 mm/s. Most films were uniform, light brown, translucent, and nonporous with some micron-size particulates. Raman and parallel electron energy loss spectroscopy indicated the presence of DLC. The films possessed favorable electron field-emission characteristics desirable for cold-cathode displays. Transmission electron microscopy (TEM) and transmission electron diffraction (TED) revealed that the C films contained diamond crystals with 25 to 125-nm grain size. BN films were composed of hexagonal, cubic and wurtzite phases.

Research Organization:
Los Alamos National Lab., NM (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-7405-ENG-36
OSTI ID:
83107
Report Number(s):
LA-UR--95-1245; CONF-950840--2; ON: DE95012076
Country of Publication:
United States
Language:
English

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