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Title: Rational Synthesis of Imprinted Organofunctional Sol-gel Materials for Toxic Metal Separation

Abstract

The objective of this program is to rationally design and synthesize imprinted sol-gel SiO2 and SiO2-MO2 (M = Ti, Zr) materials containing Si-X-L binding groups through template approaches and develop a scientific basis for metal ion binding and recognition by such tailored hybrid inorganic -organic materials. These hydrophilic oxide-based materials are expected to remove metal ions from aqueous solutions intrinsically fast (in comparison to hydrophobic organic polymers), and the imprinted binding sites are expected to exhibit enhanced recognition and binding of target RCRA metal ions.

Authors:
 [1]; ;
  1. Ben
Publication Date:
Research Org.:
University of Tennessee, Knoxville, TN; Oak Ridge National Lab., Oak Ridge, TN (US)
Sponsoring Org.:
USDOE Office of Environmental Management (EM) (US)
OSTI Identifier:
828522
Report Number(s):
EMSP-60096-2000
R&D Project: EMSP 60096; TRN: US200427%%452
DOE Contract Number:  
FG07-97ER14817
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: 1 Jun 2000
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES; AQUEOUS SOLUTIONS; DESIGN; POLYMERS; SYNTHESIS; TARGETS

Citation Formats

XUE, Ziling, Barnes, Craig E, and Dai, Sheng. Rational Synthesis of Imprinted Organofunctional Sol-gel Materials for Toxic Metal Separation. United States: N. p., 2000. Web. doi:10.2172/828522.
XUE, Ziling, Barnes, Craig E, & Dai, Sheng. Rational Synthesis of Imprinted Organofunctional Sol-gel Materials for Toxic Metal Separation. United States. doi:10.2172/828522.
XUE, Ziling, Barnes, Craig E, and Dai, Sheng. Thu . "Rational Synthesis of Imprinted Organofunctional Sol-gel Materials for Toxic Metal Separation". United States. doi:10.2172/828522. https://www.osti.gov/servlets/purl/828522.
@article{osti_828522,
title = {Rational Synthesis of Imprinted Organofunctional Sol-gel Materials for Toxic Metal Separation},
author = {XUE, Ziling and Barnes, Craig E and Dai, Sheng},
abstractNote = {The objective of this program is to rationally design and synthesize imprinted sol-gel SiO2 and SiO2-MO2 (M = Ti, Zr) materials containing Si-X-L binding groups through template approaches and develop a scientific basis for metal ion binding and recognition by such tailored hybrid inorganic -organic materials. These hydrophilic oxide-based materials are expected to remove metal ions from aqueous solutions intrinsically fast (in comparison to hydrophobic organic polymers), and the imprinted binding sites are expected to exhibit enhanced recognition and binding of target RCRA metal ions.},
doi = {10.2172/828522},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {6}
}

Technical Report:

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