New infrared solid state laser materials for CALIOPE

Conference · Mon Aug 01 04:00:00 EDT 1994

OSTI ID:82314

DeLoach, L D; Page, R H; Wilke, G D ^[1]

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1. and others

Tunable infrared laser light may serve as a useful means by which to detect the presence of the targeted effluents. Since optical parametric oscillators (OPOs) have proven to be a versatile method of generating coherent light from the ultraviolet to the mid-infrared, this technology is a promising choice by which to service the CALIOPE applications. In addition, since some uncertainty remains regarding the precise wavelengths and molecules that will be targeted, the deployment of OPOs retains the greatest amount of wavelength flexibility. Another approach that the authors are considering is that of generating tunable infrared radiation directly with a diode-pumped solid state laser (DPSSL). One important advantage of a DPSSL is that it offers flexible pulse format modes that can be tailored to meet the needs of a particular application and target molecule. On the other hand, direct generation by a tunable DPSSL will generally be able to cover a more limited wavelength range than is possible with OPO technology. In support of the CALIOPE objectives the authors are exploring the potential for laser action among a class of materials comprised of transition metal-doped zinc chalcogenide crystals (i.e., ZnS, ZnSe and ZnTe). The Cr{sup 2+}, Co{sup 2+} and Ni{sup 2+} dopants were selected as the most favorable candidates, on the basis of their documented spectral properties in the scientific literature. Thus far, the authors have characterized the absorption and emission properties of these ions in the ZnS and ZnSe crystals. The absorption spectra are used to determine the preferred wavelength at which the crystal should be pumped, while the emission spectra reveal the extent of the tuning range potentially offered by the material. In addition, measurements of the emission lifetime as a function of temperature turn out to be quite useful, since this data is suggestive of the room temperature emission yield.

• Research Organization: Lawrence Livermore National Lab., CA (United States)
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 82314
• Report Number(s): UCRL-JC--118151; CONF-9404162--20; ON: DE95014160
• Country of Publication: United States
• Language: English

Related Subjects

42 ENGINEERING
ABSORPTION SPECTRA
CHALCOGENIDES
CHROMIUM IONS
COBALT IONS
DOPED MATERIALS
EMISSION SPECTRA
INFRARED RADIATION
LASER MATERIALS
TESTING
ZINC COMPOUNDS
ZINC SELENIDES
ZINC SULFIDES
ZINC TELLURIDES