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Absolute cross sections for the electron-impact single ionization of Mo{sup 4+} and Mo{sup 5+} ions

Journal Article · · Physical Review A
;  [1]; ; ;  [2];  [3];  [4]
  1. Physics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 38731-6372 (United States)
  2. Joint Institute for Laboratory Astrophysics of the University of Colorado and the National Institute of Standards and Technology, Boulder, Colorado 80309-0440 (United States)
  3. Department of Physics, Auburn University, Auburn, Alabama 36849 (United States)
  4. Department of Physics, Rollins College, Winter Park, Florida 32789 (United States)

Absolute total cross sections for the electron-impact single ionization of Mo{sup 4+} and Mo{sup 5+} ions have been measured using a crossed-beams technique from below the ground-state ionization threshold to 500 eV with typical total uncertainties of 9% near the peak of the cross sections. Molybdenum ion production in the source was facilitated by a mini-oven sublimating MoO{sub 3}. The measured cross sections are in good agreement with distorted-wave calculations and are dominated by contributions from excitation autoionization. Nonzero cross sections below the threshold for ionization of Mo{sup 5+}(4{ital p}{sup 6}4{ital d}) ground-state ions indicate that metastable ions were present in the beam extracted from an electron-cyclotron-resonance ion source. No evidence of metastable ions was found in the case of the Mo{sup 4+} measurements. Ionization rate coefficients and fitting parameters are presented for the experimental data.

Research Organization:
Oak Ridge National Laboratory
DOE Contract Number:
AC05-84OR21400; AI05-86ER53237
OSTI ID:
82265
Journal Information:
Physical Review A, Journal Name: Physical Review A Journal Issue: 1 Vol. 52; ISSN 1050-2947; ISSN PLRAAN
Country of Publication:
United States
Language:
English

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