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Title: ''Pulling'' Nanoparticles into Water: Phase Transfer of Oleic Acid Stabilized Monodisperse Nanoparticles into Aqueous Solutions of alpha-Cyclodextrin

Abstract

(B204)This paper describes a general method to drastically improve the disparity of oleic acid stabilized nanoparticles in aqueous solutions. We use oleic acid stabilized monodisperse nanoparticles of iron oxides and silver as model systems, and have modified the surface properties of these nanoparticles through the formation of an inclusion complex between surface-bound surfactant molecules and alpha-cyclodextrin (alpha-CD). After the modification, the nanoparticles of both iron oxide and Ag can transfer from hydrophobic solvents, such as hexane, to alpha-CD aqueous phase. The efficiency of the phase transfer to the aqueous solutions depend son the initial alpha-CD concentration. The alpha-CD/oleic acid complex stabilized nanoparticles can be stable for long periods of time in aqueous phase under ambient atmospheric conditions. Transmission electron microscopy (TME), ultraviolet-visible (UV-vis) spectroscopy, Fourier transform-infrared (FT-IR) spectroscopy, and colorimetric methods have been used in the characterization of these nanoparticles.

Authors:
; ; ; ;
Publication Date:
Research Org.:
Laboratory for Laser Energetics (US)
Sponsoring Org.:
(US)
OSTI Identifier:
821202
Report Number(s):
DOE/SF-19460-507
1411; 2003-169; TRN: US200411%%10
DOE Contract Number:
FC03-92SF19460
Resource Type:
Journal Article
Resource Relation:
Journal Name: Nano Letters; Journal Volume: 3; Journal Issue: 11; Other Information: Submitted to Nano Letters: Volume 3; No.11; PBD: 18 Oct 2003
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AQUEOUS SOLUTIONS; POLYSACCHARIDES; OLEIC ACID; SURFACE PROPERTIES; SURFACTANTS; STABILIZATION; NANOSTRUCTURES; IRON OXIDES; SILVER; PHASE STUDIES

Citation Formats

Wang, Y., Wong, J.F., Teng, X., Lin, X.Z., and Yang, H. ''Pulling'' Nanoparticles into Water: Phase Transfer of Oleic Acid Stabilized Monodisperse Nanoparticles into Aqueous Solutions of alpha-Cyclodextrin. United States: N. p., 2003. Web. doi:10.1021/nl034731j.
Wang, Y., Wong, J.F., Teng, X., Lin, X.Z., & Yang, H. ''Pulling'' Nanoparticles into Water: Phase Transfer of Oleic Acid Stabilized Monodisperse Nanoparticles into Aqueous Solutions of alpha-Cyclodextrin. United States. doi:10.1021/nl034731j.
Wang, Y., Wong, J.F., Teng, X., Lin, X.Z., and Yang, H. 2003. "''Pulling'' Nanoparticles into Water: Phase Transfer of Oleic Acid Stabilized Monodisperse Nanoparticles into Aqueous Solutions of alpha-Cyclodextrin". United States. doi:10.1021/nl034731j.
@article{osti_821202,
title = {''Pulling'' Nanoparticles into Water: Phase Transfer of Oleic Acid Stabilized Monodisperse Nanoparticles into Aqueous Solutions of alpha-Cyclodextrin},
author = {Wang, Y. and Wong, J.F. and Teng, X. and Lin, X.Z. and Yang, H.},
abstractNote = {(B204)This paper describes a general method to drastically improve the disparity of oleic acid stabilized nanoparticles in aqueous solutions. We use oleic acid stabilized monodisperse nanoparticles of iron oxides and silver as model systems, and have modified the surface properties of these nanoparticles through the formation of an inclusion complex between surface-bound surfactant molecules and alpha-cyclodextrin (alpha-CD). After the modification, the nanoparticles of both iron oxide and Ag can transfer from hydrophobic solvents, such as hexane, to alpha-CD aqueous phase. The efficiency of the phase transfer to the aqueous solutions depend son the initial alpha-CD concentration. The alpha-CD/oleic acid complex stabilized nanoparticles can be stable for long periods of time in aqueous phase under ambient atmospheric conditions. Transmission electron microscopy (TME), ultraviolet-visible (UV-vis) spectroscopy, Fourier transform-infrared (FT-IR) spectroscopy, and colorimetric methods have been used in the characterization of these nanoparticles.},
doi = {10.1021/nl034731j},
journal = {Nano Letters},
number = 11,
volume = 3,
place = {United States},
year = 2003,
month =
}
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