Coordination of polythiaether macrocycles to metal cluster complexes. 2. Coordination of polythiaether macrocycles to hexaruthenium carbido carbonyl clusters
- Univ. of South Carolina, Columbia, SC (United States)
In this paper the results of the studies of complexation of three different polythiaether macrocycles, 1,5,9-trithiacyclododecane (12S3), 1,5,8,13-tetrathiacyclohexadecane (16S4) and 1,4,7-trithiacyclononane(9S3), to the hexaruthenium carbide cluster Ru{sub 6}(CO){sub 17}-({mu}{sub 6}-Cl) are described. These studies further demonstrate that the thiaether ligands are able to change their conformations in order to serve as more effective ligands. 18 refs., 4 figs., 13 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 81419
- Journal Information:
- Organometallics, Journal Name: Organometallics Journal Issue: 4 Vol. 14; ISSN 0276-7333; ISSN ORGND7
- Country of Publication:
- United States
- Language:
- English
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