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Low-energy electron diffraction study of the thermal expansion of Ag(111)

Journal Article · · Surface Science

The temperature dependence of the first three interlayer distances of the Ag(111) surface was studied by low-energy electron diffraction (LEED) over the temperature range 128K to 723 K. The first three interlayer spacings and the effective Debye temperatures were extracted from the LEED analysis. At the lowest temperature, the first two interlayer spacings are slightly (0.5 percent) contracted. All three interlayer spacings increase with temperature, finally reaching expansions relative to the bulk of about 0.8 percent at the highest temperature studied. The effective surface Debye temperature is lowest for the outermost layer, increasing toward the bulk value for successive layers.

Research Organization:
Ernest Orlando Lawrence Berkeley National Lab., CA (US)
Sponsoring Organization:
USDOE Director, Office of Science. Office of Basic Energy Studies. Division of Materials Sciences (US)
DOE Contract Number:
AC03-76SF00098
OSTI ID:
793781
Report Number(s):
LBNL--49718
Journal Information:
Surface Science, Journal Name: Surface Science Vol. 468; ISSN SUSCAS; ISSN 0039-6028
Country of Publication:
United States
Language:
English