Scanning tunneling microscopy studies of organic monolayers adsorbed on the rhodium(111) crystal surface
- Univ. of California, Berkeley, CA (United States); LBNL Library
Scanning Tunneling Microscopy studies were carried out on ordered overlayers on the (111) surface of rhodium. These adsorbates include carbon monoxide (CO), cyclohexane, cyclohexene, 1,4-cyclohexadiene, para-xylene, and meta-xylene. Coadsorbate systems included: CO with ethylidyne, CO with para- and meta-xylene, and para-xylene with meta-xylene. In the case of CO, the structure of the low coverage (2x2) overlayer has been observed. The symmetry of the unit cell in this layer suggests that the CO is adsorbed in the 3-fold hollow sites. There were also two higher coverage surface structures with (√7x√7) unit cells. One of these is composed of trimers of CO and has three CO molecules in each unit cell. The other structure has an additional CO molecule, making a total of four. This extra CO sits on a top site.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- DOE Contract Number:
- AC03-76SF00098
- OSTI ID:
- 760334
- Report Number(s):
- LBNL--44194
- Country of Publication:
- United States
- Language:
- English
Similar Records
A surface science study of the hydrogenation and dehydrogenation steps in the interconversion of C{sub 6} cyclic hydrocarbons on Ni(100)
Site blocking effects in ethylidyne decomposition kinetics on Ru(001). In-situ study with infrared reflection absorption spectroscopy at elevated pressure