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New Fecal Method for Plutonium and Americium

Journal Article · · Analytical Chemistry
OSTI ID:757622

A new fecal analysis method that dissolves plutonium oxide was developed at the Westinghouse Savannah River Site. Diphonix Resin (Eichrom Industries), is used to pre-concentrate the actinides from digested fecal samples. A rapid microwave digestion technique is used to remove the actinides from the Diphonix Resin, which effectively extracts plutonium and americium from acidic solutions containing hydrofluoric acid. After resin digestion, the plutonium and americium are recovered in a small volume of nitric acid that is loaded onto small extraction chromatography columns, TEVA Resin and TRU Resin (Eichrom Industries). The method enables complete dissolution of plutonium oxide and provides high recovery of plutonium and americium with good removal of thorium isotopes such as thorium-228.

Research Organization:
Savannah River Site (US)
Sponsoring Organization:
US Department of Energy (US)
DOE Contract Number:
AC09-96SR18500
OSTI ID:
757622
Report Number(s):
WSRC-MS-2000-00314
Journal Information:
Analytical Chemistry, Journal Name: Analytical Chemistry
Country of Publication:
United States
Language:
English

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