Hydrodechlorination of 1,1,2-trichloro-1,2,2-trifluoroethane over a nickel catalyst prepared from TiNiH{sub x}
Journal Article
·
· Kinetics and Catalysis
OSTI ID:75550
- Moscow State Univ. (Russian Federation)
Supported Ni/TiO{sub 2} catalysts are prepared by treating Ti-Ni-H{sub x} hydrides with concentrated hydrochloric acid. The catalysts were then tested in hydrodechlorination of 1,1,2-trichloro-1,2,2-trifluoroethane (freon R-113) into chlorofluoroethylene. The samples were obtained with various specific surface areas and nickel contents depending on the treatment conditions. The catalyst with 8.3% Ni and S{sub sp} = 289 m{sup 2}/g exhibits the maximal activity and stability. The effect of the strong metal-support interaction (SMSI) on the activity of the catalysts studied in hydrodechlorination is discussed.
- OSTI ID:
- 75550
- Journal Information:
- Kinetics and Catalysis, Journal Name: Kinetics and Catalysis Journal Issue: 1 Vol. 36; ISSN 0023-1584; ISSN KICAA8
- Country of Publication:
- United States
- Language:
- English
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