Low-temperature interaction of U(IV) and XeO{sub 3} in frozen aqueous H{sub 2}SO{sub 4} solutions accompanied by chemiluminescence
Journal Article
·
· Kinetics and Catalysis
OSTI ID:75521
- Institute of Organic Chemistry, Bashkortostan (Russian Federation)
Low-temperature (T{ge}180K) oxidation of U(IV) by xenon trioxide accompanied by chemiluminescence is studied in a frozen 0.2 M H{sub 2}SO{sub 4} solution. It is shown that the peak of luminescence at 195-200 K is related to chemiluminescence of the excited uranyl ion (UO{sup 2+}{sub 2}) formed in the oxidation of U(V), an intermediate product of the interaction of U(IV) and XeO{sub 3}.
- OSTI ID:
- 75521
- Journal Information:
- Kinetics and Catalysis, Vol. 36, Issue 2; Other Information: PBD: Mar-Apr 1995; TN: Translated from Kinetika i Kataliz; 36: No. 2, 198-202(1995)
- Country of Publication:
- United States
- Language:
- English
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