Phase transformation and growth of hygroscopic aerosols

Book · Mon Nov 01 04:00:00 EST 1999

OSTI ID:752145

Tang, I N ^[1]

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1. BROOKHAVEN NATIONAL Lab.

Ambient aerosols play an important role in many atmospheric processes affecting air quality, visibility degradation, and climatic changes as well. Both natural and anthropogenic sources contribute to the formation of ambient aerosols, which are composed mostly of sulfates, nitrates, and chlorides in either pure or mixed forms. These inorganic salt aerosols are hygroscopic by nature and exhibit the properties of deliquescence and efflorescence in humid air. For pure inorganic salt particles with diameter larger than 0.1 micron, the phase transformation from a solid particle to a saline droplet occurs only when the relative humidity in the surrounding atmosphere reaches a certain critical level corresponding to the water activity of the saturated solution. The droplet size or mass in equilibrium with relative humidity can be calculated in a straightforward manner from thermodynamic considerations. For aqueous droplets 0.1 micron or smaller, the surface curvature effect on vapor pressure becomes important and the Kelvin equation must be used.

• Research Organization: Brookhaven National Lab., Upton, NY (US)
• Sponsoring Organization: USDOE Office of Energy Research (ER) (US)
• DOE Contract Number: AC02-98CH10886
• OSTI ID: 752145
• Report Number(s): BNL--62295-99/11-REV; KC030202
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
AEROSOLS
ATMOSPHERIC CHEMISTRY
DROPLETS
HUMIDITY
PARTICLE SIZE
PHASE TRANSFORMATIONS