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Title: Leaching characteristics of the metal waste form from the electrometallurgical treatment process: Product consistency testing

Conference ·
OSTI ID:750586

Argonne National Laboratory is developing an electrometallurgical treatment for spent fuel from the experimental breeder reactor II. A product of this treatment process is a metal waste form that incorporates the stainless steel cladding hulls, zirconium from the fuel and the fission products that are noble to the process, i.e., Tc, Ru, Nb, Pd, Rh, Ag. The nominal composition of this waste form is stainless steel/15 wt% zirconium/1--4 wt% noble metal fission products/1--2 wt % U. Leaching results are presented from several tests and sample types: (1) 2 week monolithic immersion tests on actual metal waste forms produced from irradiated cladding hulls, (2) long term (>2 years) pulsed flow tests on samples containing technetium and uranium and (3) crushed sample immersion tests on cold simulated metal waste form samples. The test results will be compared and their relevance for waste form product consistency testing discussed.

Research Organization:
Argonne National Lab., IL (US)
Sponsoring Organization:
US Department of Energy (US)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
750586
Report Number(s):
ANL/NT/CP-100472; TRN: US0003340
Resource Relation:
Conference: MRS '99 Fall Meeting, Boston, MA (US), 11/29/1999--12/03/1999; Other Information: PBD: 11 Nov 1999
Country of Publication:
United States
Language:
English