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Title: Direct chlorination process for hydrogen sulfide abatement

Conference ·
OSTI ID:7369592

The Direct Chlorination Process removes hydrogen sulfide from geothermal off-gases by reacting hydrogen sulfide with chlorine in the gas phase. Hydrogen chloride and elemental sulfur are formed by this reaction. The Direct Chlorination Process has been successfully demonstrated by an on-site operation of a pilot plant at the 3 MWe HPG-A geothermal power plant in Hawaii. Over 99.5% hydrogen sulfide removal was achieved in a single cocurrent reaction stage. Chlorine gas did not escape the pilot plant, even when 90% excess chlorine gas was used. A preliminary economic evaluation indicates that, when compared with the Stretford Process, the Direct Chlorination Process required about one-third the initial capital investment and about one-fourth the net daily expenditure. Because of the higher cost of chemicals and the restricted markets in Hawaii, the economic viability of this process in Hawaii is questionable.

Research Organization:
I. Sheinbaum Company, Inc., Monrovia, CA
OSTI ID:
7369592
Report Number(s):
EPRI-AP-3271; CONF-8306177-; ON: TI84920082
Resource Relation:
Conference: 7. annual geothermal conference and workshop, San Diego, CA, USA, 28 Jun 1983; Related Information: In: Seventh annual geothermal conference and workshop: proceedings, by
Country of Publication:
United States
Language:
English