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Mercury photosensitized production of trapped radicals in organic glasses at less than or equal to 77 K

Conference ·
OSTI ID:7361591
; ; ;
Solutions of Hg in liquid hydrocarbons may be stabilized in the glassy state by quench cooling in liquid nitrogen at 77/sup 0/K. The results of a study of the kinetics of photo-induced radical formation and decay in a glassy solution in 3-methylpentane are briefly reported. The implications of these results for additional experimental studies are tabulated. (JSR)
Research Organization:
Wisconsin Univ., Madison (USA). Dept. of Chemistry
OSTI ID:
7361591
Report Number(s):
COO-1715-237; CONF-760620-1
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
ALKANES
ALKYL RADICALS
CHEMICAL REACTION KINETICS
CHEMISTRY
ELEMENTS
HYDROCARBONS
KINETICS
LOW TEMPERATURE
MERCURY
METALS
ORGANIC COMPOUNDS
PHOTOCHEMISTRY
RADICALS
REACTION KINETICS
ULTRALOW TEMPERATURE
VERY LOW TEMPERATURE