Electron spin resonance of electron irradiated Ni(CN)/sub 4/K/sub 2/ in KCl
Journal Article
·
· J. Chem. Phys.; (United States)
OSTI ID:7355362
Single crystals of KCl doped with Ni(CN)/sub 4/K/sub 2/ 0.02M were irradiated with 2 MeV electrons. ESR studies of the samples with 70% of /sup 13/C reveal the existence of four species assigned to be Ni(CN)/sub 4/Cl/sub 2//sup 3 -/ and Ni(CN)/sub 4/Cl/sub 2//sup 5 -/ in the isomeric states cis and trans. The form of the g and A tensors is discussed, and it indicates that the great anisotropies observed in the cis species are due to the influence of the vacancy created by charge compensation. (AIP)
- Research Organization:
- Universidade Federal de Sao Carlos, Sao Paulo, Brazil
- OSTI ID:
- 7355362
- Journal Information:
- J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 64:8; ISSN JCPSA
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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Journal Article
·
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· J. Chem. Phys., v. 59, no. 8, pp. 4418-4422
·
OSTI ID:4328019
Related Subjects
36 MATERIALS SCIENCE
360605* -- Materials-- Radiation Effects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600 -- Radiation Chemistry
ALKALI METAL COMPOUNDS
BEAMS
CHEMICAL RADIATION EFFECTS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
CRYSTALS
DOPED MATERIALS
ELECTRON BEAMS
ELECTRON SPIN RESONANCE
ENERGY RANGE
HALIDES
HALOGEN COMPOUNDS
LEPTON BEAMS
MAGNETIC RESONANCE
MEV RANGE
MEV RANGE 01-10
MONOCRYSTALS
PARTICLE BEAMS
POTASSIUM CHLORIDES
POTASSIUM COMPOUNDS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RESONANCE
360605* -- Materials-- Radiation Effects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600 -- Radiation Chemistry
ALKALI METAL COMPOUNDS
BEAMS
CHEMICAL RADIATION EFFECTS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
CRYSTALS
DOPED MATERIALS
ELECTRON BEAMS
ELECTRON SPIN RESONANCE
ENERGY RANGE
HALIDES
HALOGEN COMPOUNDS
LEPTON BEAMS
MAGNETIC RESONANCE
MEV RANGE
MEV RANGE 01-10
MONOCRYSTALS
PARTICLE BEAMS
POTASSIUM CHLORIDES
POTASSIUM COMPOUNDS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RESONANCE