Photochemical synthesis of peroxyacyl nitrates in gas phase via chlorine--aldehyde reaction. [Peroxyacetyl nitrate]
Journal Article
·
· Environ. Sci. Technol.; (United States)
A new peroxyacyl nitrate synthesis in the gas phase has been developed. Molecular chlorine is photolyzed to yield chlorine atoms that abstract aldehydic hydrogen from the aldehyde. The acyl radical then adds oxygen and nitrogen dioxide to form the PAN. Any member of the PAN family can thus be produced from its parent aldehyde cleanly and in very high yield.
- Research Organization:
- Environmental Research Center, Research Triangle Park, NC
- OSTI ID:
- 7353044
- Journal Information:
- Environ. Sci. Technol.; (United States), Journal Name: Environ. Sci. Technol.; (United States) Vol. 10:1; ISSN ESTHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
500200 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
AIR POLLUTION
ALDEHYDES
AUTOMOBILES
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
CHLORINE
DECOMPOSITION
ELEMENTS
EXHAUST GASES
GASEOUS WASTES
HALOGENS
HYDROCARBONS
NITRATES
NITROGEN COMPOUNDS
NITROGEN OXIDES
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL OXIDANTS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
PHOTOLYSIS
POLLUTION
SMOG
SYNTHESIS
VEHICLES
WASTES
400500* -- Photochemistry
500200 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
AIR POLLUTION
ALDEHYDES
AUTOMOBILES
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
CHLORINE
DECOMPOSITION
ELEMENTS
EXHAUST GASES
GASEOUS WASTES
HALOGENS
HYDROCARBONS
NITRATES
NITROGEN COMPOUNDS
NITROGEN OXIDES
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL OXIDANTS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
PHOTOLYSIS
POLLUTION
SMOG
SYNTHESIS
VEHICLES
WASTES