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Coal processing: NO/sub x/ formation during gas combustion

Journal Article · · Chem. Eng. Prog.; (United States)
OSTI ID:7336537
The overall conversion of coal nitrogen to NO/sub x/ in a gasification/combustion process was significantly less than that which occurs in the direct burning of pulverized coal. These test results indicate that it was smaller by about a factor of two. NO/sub x/ emissions due to the fixation of atmospheric nitrogen from the combustion of low Btu gas were observed to be between 90 and 140 ppM for both diffusion and pre-mixed flames. NO/sub x/ emissions were found to be a direct function of both furnace excess oxygen and measured amounts of NH/sub 3/ in the fuel gas. In the results reported, the conversion of NH/sub 3/ to NO/sub x/ contributed between 60 to 180 ppM to the total level of emissions. The conversion efficiency of NH/sub 3/ to NO/sub x/ varied inversely with NH/sub 3/ concentration to the burner. At low NH/sub 3/ concentrations (0 to 2000 ppM) the conversion of NH/sub 3/ to NO/sub x/ in a laboratory premixed flame was approximately twice that observed in a diffusion flame.
Research Organization:
Riley Stoker Corp., Worcester, MA
OSTI ID:
7336537
Journal Information:
Chem. Eng. Prog.; (United States), Journal Name: Chem. Eng. Prog.; (United States) Vol. 72:8; ISSN CEPRA
Country of Publication:
United States
Language:
English