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Oxidation product in glycine AgNO/sub 3/. [X rays]

Journal Article · · J. Chem. Phys.; (United States)
OSTI ID:7330464
A primary oxidation product in x-irradiated single crystals of glycine silver nitrate at 4.2/sup 0/K was studied by ESR and ENDOR spectroscopy. The main consequence of the oxidation process is to create an electron deficiency shared by two silver ions and the surrounding carboxylic groups. The delocalized unpaired electron interacts with the two silver nuceli, /sup 107/Ag and/or /sup 109/Ag, separated by 2.88 A. The principal values for the g and hyperfine tensors for /sup 107/Ag and /sup 109/Ag were determined. The highly anisotropic triplet ESR absorption spectrum disappears at 65degreeK.
Research Organization:
Department of Biophysics, Roswell Park Memorial Institute, Buffalo, New York 14263
OSTI ID:
7330464
Journal Information:
J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 66:5; ISSN JCPSA
Country of Publication:
United States
Language:
English