Superconductivity and phase stability of Nb/sub 3/Ge
- Brookhaven National Lab., Upton, NY
The A-15 phase of chemically vapor-deposited Nb/sub 3/Ge has been investigated by annealing techniques in the temperature range 700 to 1450/sup 0/C and by irradiation with high-energy neutrons (E greater than 1 MeV). By x-ray diffraction analysis the samples were found to contain about 55 wt percent of the A-15 phase, 35 wt percent of tetragonal Nb/sub 5/Ge/sub 3/, and minor amounts of NbO/sub 2/, NbO, and hexagonal Nb/sub 5/Ge/sub 3/. The superconducting transition temperature T/sub c/ and lattice parameter a/sub o/ of the A-15 phase have been measured as a function of annealing temperature and neutron irradiation. T/sub c/ for the unirradiated sample remained above 19/sup 0/K for long-term anneals in the temperature range 700 to 1000/sup 0/C but decreased rapidly above 1000/sup 0/C, reaching a limiting value of about 6/sup 0/K at 1250/sup 0/C, compared to the as-deposited value of about 20/sup 0/K. The decrease in T/sub c/ was accompanied by an increase in a/sub o/ and an increase in the amount of tetragonal Nb/sub 5/Ge/sub 3/ to about 50 wt percent. The observed decrease in T/sub c/ was irreversible in that subsequent annealing at 1100/sup 0/C did not result in any increase in T/sub c/ or decrease in a/sub o/. The sample having a T/sub c/ of about 21/sup 0/K was found to exhibit no superconductivity to 1.5/sup 0/K after exposure to a fluence of approximately 5 x 10/sup 19/ n/cm/sup 2/. An increase in a/sub o/ was also found as a function of neutron irradiation. However, in this case the effects were reversible. It is concluded that the stoichiometric composition is metastable and upon annealing transforms to a stable, Nb-rich A-15 phase containing about 83 at. percent Nb with a T/sub c/ of approximately 6/sup 0/K accompanied by precipitation of tetragonal Nb/sub 5/Ge/sub 3/.
- OSTI ID:
- 7324933
- Journal Information:
- J. Low Temp. Phys.; (United States), Vol. 24:5/6
- Country of Publication:
- United States
- Language:
- English
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SUPERCONDUCTIVITY AND SUPERFLUIDITY
GERMANIUM ALLOYS
PHYSICAL RADIATION EFFECTS
TRANSITION TEMPERATURE
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ANNEALING
BINARY ALLOY SYSTEMS
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INTERMETALLIC COMPOUNDS
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FERMIONS
HADRONS
HEAT TREATMENTS
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NEUTRONS
NUCLEONS
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SCATTERING
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