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LWR fuel reprocessing and recycle progress report for July 1--September 30, 1976. [Off-gas treatment; waste management; /sup 129/I adsorbent and storage]

Technical Report ·
OSTI ID:7320566

LWR Off-Gas Treatment: A reference facility has been described in a draft report. A survey of technical literature for immobilization of /sup 14/CO/sub 2/ was completed. Waste Management: Laboratory evaporations were continued using simulated HLLW solutions representing three fuel cycle processes. Total solids content at various degrees of evaporation are presented together with boiling point rises and slurry densities. Substitution of less costly materials for Rh, Pd, and Tc did not affect the physical properties of the slurries or the quantity of solids formed. The effect of adding nuclear poisons (gadolinium, boron, or cadmium) on physical properties of HLLW and on solids formation is reported. Solids formed in all HLLW solutions contained major amounts of Zr and Mo. The design of the small-scale thermosyphon evaporator and the reboiler tube test specimen are presented. Evaporated HLLW slurries stored for two months at 35/sup 0/C have not produced significantly more solids. Laboratory corrosion data showed excessive corrosion occurred in HLLW containing high iron concentrations and 7 M HNO/sub 3/, apparently due to Cr formed by stainless steel corrosion. Iodine-129 Adsorbent and Storage Development: Silver-exchanged zeolite (AgX) and mordenite (AgZ) were loaded with and stripped of elemental iodine for evaluation for recycle behavior. After five cycles, the AgZ showed no decrease in loading (approximately 440 mg/g); the AgX loading dropped about 50 percent from its initial value of 320 mg/g. (DLC)

Research Organization:
Idaho National Engineering Lab., Idaho Falls (USA)
DOE Contract Number:
EY-76-C-07-1540
OSTI ID:
7320566
Report Number(s):
ICP-1108
Country of Publication:
United States
Language:
English