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Magnetic properties of the AnFe/sub 2/ compounds (An = U, Np, Pu, and Am)

Conference ·
OSTI ID:7317844

The magnetic properties of the actinide Laves compounds (cubic C-15 crystal structure) with iron were studied by magnetization, neutron diffraction, and Moessbauer-effect techniques. All the compounds exhibit a spontaneous magnetization. Magnetic moments of 0.06, 1.09, 0.45, and -0.4..mu../sub B/ are associated with the U, Np, Pu, and Am ions, respectively. The corresponding iron moments are 0.6, 1.4, 1.5, and 1.7..mu../sub B/. The ferrimagnetic nature of AmFe/sub 2/ suggests a partial occupancy of the Am/sup 2 +/:f/sup 7/ state, inasmuch as the Am/sup 3 +/:f/sup 6/ state has a nonmagnetic ground state.

Research Organization:
Argonne National Lab., IL (USA)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
7317844
Report Number(s):
CONF-760922-15
Country of Publication:
United States
Language:
English