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Room-temperature desorption of /sup 3/He from metal tritides: A tritium concentration effect on the rapid release of helium from the tritide

Journal Article · · J. Vac. Sci. Technol.; (United States)
DOI:https://doi.org/10.1116/1.569291· OSTI ID:7317762
It has long been known that /sup 3/He accumulates in metal tritides as tritium decays. Early in life nearly 100% of the /sup 3/He is retained in the lattice. It has also been noted that as a critical concentration is reached (material dependent) the lattice will no longer retain the /sup 3/He, and it is emitted at about the generation rate. We have recently made measurements on a number of erbium tritides with varying concentrations in the ditritide phase. The expected early release characteristics are observed for all of the samples. However, ditritides with higher tritium concentrations reach the rapid release state at much lower /sup 3/He concentrations. For instance, the helium-to-metal concentration for rapid release in the unsaturated ditritide is about 0.22, whereas it is only one-tenth this value in the saturated ditritide. The additional tritium in the tritide appears to be the cause of the this effect.
Research Organization:
Sandia Laboratories, Albuquerque, New Mexico 87115
OSTI ID:
7317762
Journal Information:
J. Vac. Sci. Technol.; (United States), Journal Name: J. Vac. Sci. Technol.; (United States) Vol. 14:1; ISSN JVSTA
Country of Publication:
United States
Language:
English