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Soft chemical synthesis of new compounds with the hexagonal molybdenum oxide structure

Journal Article · · Chemistry of Materials; (United States)
DOI:https://doi.org/10.1021/cm00018a012· OSTI ID:7305520
;  [1]
  1. Univ. of Pennsylvania, Philadelphia (United States)
In the current work, the authors have found that the alkali-metal brannerites undergo a novel leaching' reaction, which for A = Li leads to the formation of H{sub 0.13}V{sub 0.13}Mo{sub 0.87}O{sub 3}{center dot}nH{sub 2}O. Subsequent dehydration of this compound permits the preparation of a microporous' form of hexagonal MoO{sub 3}, V{sub 0.13}Mo{sub 0.87}O{sub 2.935}, in which the one-dimensional tunnels are empty.
OSTI ID:
7305520
Journal Information:
Chemistry of Materials; (United States), Journal Name: Chemistry of Materials; (United States) Vol. 3:6; ISSN CMATE; ISSN 0897-4756
Country of Publication:
United States
Language:
English

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